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SOFCs BASED ON SrCe_(0.95)Yb_(0.05)O_3 PROTON CONDUCTOR

机译:基于SrCe_(0.95)Yb_(0.05)O_3质子导体的SOFC

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A fuel cell was constructed using proton-conducting perovskite SrCe_(0.95)Yb_(0.05)O_(3-). The solid electrolyte was coated with symmetrical Pt electrodes using magnetron sputtering. The fuel cell was tested using methane and hydrogen under dry and wet (3% water saturation) conditions. This study has shown that hydrogen provided lower resistance in terms of electrode processes and hence a higher power output. Methane under dry conditions resulted in particularly poor performance as a result of slow decomposition to hydrogen and there was physical evidence of carbon deposition inside the fuel cell. The production of hydrogen took place much more readily under wet methane by reforming, and this was reflected in a performance approaching that of the hydrogen fuel.
机译:使用质子传导钙钛矿SrCe_(0.95)Yb_(0.05)O_(3-)构建燃料电池。使用磁控溅射将固体电解质涂有对称的Pt电极。使用甲烷和氢气在干燥和潮湿(水饱和度3%)条件下测试了燃料电池。这项研究表明,就电极工艺而言,氢提供了较低的电阻,因此提供了更高的功率输出。甲烷在干燥条件下由于缓慢分解为氢而导致特别差的性能,并且有物理证据表明碳在燃料电池内部沉积。通过重整,在湿甲烷下更容易产生氢,这体现在接近氢燃料的性能上。

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