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PREPARATION OF MESOPOROUS AND MACROPOROUS MATERIALS FOR SOLID OXIDE FUEL CELLS

机译:固体氧化物燃料电池介孔和大孔材料的制备

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Mesoporous yttria-stabilized zirconia (YSZ) and YSZ-NiO thermally stable up to 600 ℃ have been prepared using an anionic surfactant as a structure-directing agent and inorganic nitrates as precursors. Mesoporous YSZ has high sinterability; the relative density of the YSZ sintered at 1250 ℃ is 94 %. The interfacial resistance between a dense YSZ electrolyte and mesoporous YSZ-Ni-Pt anode is about 2.8Ωcm~2 at 600 ℃. Ordered macroporous Sr_(0.5)Sm_(0.5)CoO_3 structrures with an average pore size of 140 nm have been prepared using closed-packed arrangement of monodispersed polystyrene spheres as templates. A fuel cell using ordered macroporous Sr_(0.5)Sm_(0.5)CoO_3 as the cathode, gadolinia-doped ceria (GDC) film as the electrolyte, and GDC-Ni as the anode generated maximum power densities of 150, 196 and 267 mW/cm~2 at 500, 550 and 600℃, respectively.
机译:以阴离子表面活性剂为结构导向剂,以无机硝酸盐为前驱体制备了介孔氧化钇稳定的氧化锆(YSZ)和热稳定至600℃的YSZ-NiO。介孔YSZ具有高烧结性;在1250℃烧结的YSZ的相对密度为94%。致密的YSZ电解质与介孔YSZ-Ni-Pt阳极在600℃时的界面电阻约为2.8Ωcm〜2。使用单分散聚苯乙烯球体的密排排列,制备了平均孔径为140 nm的有序大孔Sr_(0.5)Sm_(0.5)CoO_3结构。使用有序大孔Sr_(0.5)Sm_(0.5)CoO_3作为阴极,掺杂氧化lin的二氧化铈(GDC)膜作为电解质,使用GDC-Ni作为阳极的燃料电池产生的最大功率密度分别为150、196和267 mW /在500、550和600℃分别为cm〜2。

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