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Effect of nano-SiO_2 on the rheology of anionic viscoelastic solutions formed by the biodegradable surfactant fatty acid methyl ester sulfonate

机译:纳米SiO_2对可生物降解的表面活性剂脂肪酸甲酯磺酸盐形成的阴离子粘弹性溶液流变性的影响

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The effects of nano-SiO_2 on the rheology of viscoelastic solutions formed by the biodegradable surfactant fatty acid methyl ester sulfonate (MES) were studied. The process of MES micelles transforming from sphere or rod to wormlike was investigated with the increase in NaCl concentration by rheological measurements. The increase in η0 on the introduction of SiO_2 was explained by considering the increasingly entangled wormlike micelles that were formed due to the screening of the electrostatic interactions. The results of rheological measurements show that the system of MES /NaCl can transform into wormlike micelles. MES micelle solutions without SiO_2 are linear viscoelastic fluids in accord with a Maxwell model having a single relaxation time. But there is a process with some distributions of the relaxation time for MES micelle solution with SiO_2.
机译:研究了纳米SiO_2对可生物降解的表面活性剂脂肪酸甲酯磺酸盐(MES)形成的粘弹性溶液流变学的影响。通过流变学测量研究了随着NaCl浓度的增加,MES胶束从球形或棒状转变为蠕虫状的过程。考虑到由于静电相互作用的筛选而形成的越来越纠缠的蠕虫状胶束,解释了SiO_2引入时η0的增加。流变学结果表明,MES / NaCl体系可以转化为蠕虫状的胶束。不含SiO_2的MES胶束溶液是线性粘弹性流体,符合具有单个弛豫时间的Maxwell模型。但是,对于具有SiO_2的MES胶束溶液,存在弛豫时间有一定分布的过程。

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