SEPARATION OF ISOPRENE COMPOUNDS VIA π -COMPLEXATION IN C5 MIXTURES

机译：在C5混合物中通过π络合分离异戊二烯化合物

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Olefin/paraffin separation is one of the most important processes in the petrochemical industry. The conventional method for separating olefin/paraffin mixtures has been highly energy-intensive and low-temperature distillation. A process based upon reversible chemical complexation (e.g. π-complexation), which employs a mass-separating agent rather than an energy-separating agent, presents an attractive alternative to distillation. Use of such a reversible olefin complexation process could substantially reduce the capital costs and energy requirements of olefin/paraffin separations. We investigated liquid-liquid separation system using copper ions as a selective separating agent.

机译：烯烃/石蜡分离是石化工业中最重要的过程之一。分离烯烃/链烷烃混合物的常规方法是高能量消耗和低温蒸馏。基于可逆化学络合（例如，π-络合）的方法，采用质量分离剂而不是能量分离剂，是蒸馏的有吸引力的替代方案。使用这种可逆的烯烃络合方法可以大大降低烯烃/石蜡分离的投资成本和能量需求。我们研究了使用铜离子作为选择性分离剂的液-液分离系统。

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《Frontiers on Separation Science and Technology》|2004年|P.186-191|共6页
会议地点 Nanning(CN)
作者
S. J. SON; S. W. KIM; D. K. CHOI; H. S. KIM; Y. J. KIM; S. H. KIM;
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Dept. of Chemical Biological Engineering, Korea University 1,5-Ka, Anam-dong, Seongbuk-ku, Seoul, 136-701, Korea;

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正文语种 eng
中图分类分离过程;
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机译：通过pi络合物在C_5混合物中分离异戊二烯化合物
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3. Selective separation of fluorinated compounds from complex organic mixtures by pyrolysis-comprehensive two-dimensional gas chromatography coupled to high-resolution time-of-flight mass spectrometry [J] . Yoji Nakajima, Yuko Arinami, Kiyoshi Yamamoto Research reports of Asahi Glass Co.,Ltd. . 2015,第期

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4. SEPARATION OF ISOPRENE COMPOUNDS VIA π-COMPLEXATION IN C5 MIXTURES [C] . Stanford A.Young Frontiers on Separation Science and Technology . 2004

机译：通过C5混合物中的π络合物分离异戊二烯化合物
5. High Speed Separations of Complex Mixtures using nano-Liquid Chromatography Coupled with micro Free Flow Electrophoresis. [D] . Geiger, Matthew. 2016

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6. Metal-organic framework and Tenax-TA as optimal sorbent mixture for concurrent GC-MS analysis of C1 to C5 carbonyl compounds [O] . Tanushree Dutta, Ki-Hyun Kim, Richard J. C. Brown, -1

机译：金属有机骨架和Tenax-TA是同时进行GC-MS分析C1至C5羰基化合物的最佳吸附剂混合物
7. Separation and Purification of Isoprene from C5-Olefin Mixtures by the Cuprous Chloride-Diene Reaction [O] . Hiroyuki NISHIKAWA, Osamu INOMATA 1967

机译：通过氯化亚铜 - 二烯反应从C5-烯烃混合物中分离和纯化异戊二烯
8. Pilot Study on International Information Exchange on Dioxins and Related Compounds. Scientific Basis for the Development of the International Toxicity Equivalency Factor (I-TEF) Method of Risk Assessment for Complex Mixtures of Dioxins and Related Compounds [R] . Safe, S. H., Kutz, F. W., Bottimore, D. P. 1988

机译：国际信息交换二恶英及相关化合物的初步研究。开发国际毒性当量因子（I-TEF）二恶英和相关化合物复杂混合物风险评估方法的科学依据

SEPARATION OF ISOPRENE COMPOUNDS VIA π -COMPLEXATION IN C5 MIXTURES

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