TOPOCHEMICAL SOLID-PHASE REACTIONS OF FLUORINATION AND THE PROBLEMS OF SELECTIVE FUNCTIONALIZATION OF FULLERENES WITH SMALL INORGANIC GROUPS

机译：氟化的固相固相反应和具有少量无机基团的富勒烯的选择性功能化问题

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Comparison studies of C_(60) fluorination with solid binary (MeF_n) or complex (M_kMeF_n) metal fluorides and with elemental fluorine under low-pressure conditions was conducted by means of electron impact mass spectrometry, using Knudsen cell as a reactor. All the reactions are accompanied by distillation of the volatile products C_(60)F_(2m). The results are discussed in the framework of the developed kinetic model, offering an explanation of the observed facts. The reasons and conditions for selectivity have been recognized.

机译：使用Knudsen池作为反应器，通过电子碰撞质谱法在低压条件下与固态二元（MeF_n）或配合物（M_kMeF_n）氟化物与元素氟进行C_（60）氟化的比较研究。所有反应都伴随有挥发性产物C_（60）F_（2m）的蒸馏。在已开发的动力学模型的框架中讨论了结果，为观察到的事实提供了解释。选择性的原因和条件已得到认可。

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《Fullerenes and Nanotubes: The Building Blocks of Next Generation Nanodevices: Fullorenes》|2003年|P.225-238|共14页
会议地点 Paris(FR);Paris(FR);Paris(FR)
作者
A.Ya.Borschevskii; N.S.Chilingarov; L.N.Sidorov;
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作者单位

Chemistry Department, Moscow State University, Moscow 119992, Russia;

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原文格式 PDF
正文语种 eng
中图分类无机高分子化合物（高聚物）;
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TOPOCHEMICAL SOLID-PHASE REACTIONS OF FLUORINATION AND THE PROBLEMS OF SELECTIVE FUNCTIONALIZATION OF FULLERENES WITH SMALL INORGANIC GROUPS

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