THE PREPARATION OF FULLERENES - A CASE OF INTERDISCIPLINARY RESEARCH

机译：富勒烯的制备-跨学科研究

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Interstellar molecules and dust particles play an important role in astronomy and astrophysics. From astronomical observations, the optical and infrared absorption spectra of interstellar matter are fairly well known, however, the structure and chemical composition of most of the absorbers is still puzzling. Carbon as the most abundant condensable element in space should be a major constituent of interstellar grains. To check for the presence of graphitic interstellar dust, we produced carbon nanoparticles in the laboratory and tried to match the obtained optical absorptions with astronomical features. In the course of this investigation carried out in collaboration with Donald R. Huffman from the University of Arizona we discovered a method of producing fullerenes in bulk quantities. In this paper, the main steps of the discovery will be outlined again and a brief account will be given of the avalanche of research which followed, highlighting some of the major discoveries.

机译：星际分子和尘埃粒子在天文学和天体物理学中起着重要作用。从天文观测，星际物质的光学和红外吸收光谱是众所周知的，但是，大多数吸收器的结构和化学组成仍然令人费解。碳是空间中最丰富的可冷凝元素，应该是星际谷物的主要成分。为了检查是否存在石墨星际尘埃，我们在实验室中生产了碳纳米颗粒，并尝试将获得的光吸收与天文特性进行匹配。在与亚利桑那大学的Donald R. Huffman合作进行的调查过程中，我们发现了一种批量生产富勒烯的方法。在本文中，将再次概述该发现的主要步骤，并简要介绍随后的大量研究，重点介绍了一些主要发现。

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《Fullerenes and Nanotubes: The Building Blocks of Next Generation Nanodevices: Fullorenes》|2003年|P.1-8|共8页
会议地点 Paris(FR);Paris(FR);Paris(FR)
作者
Wolfgang Kraetschmer;
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Max-Planck-Institut fuer Kernphysik, D-69029 Heidelberg, P.O. Box 103980, Germany;

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原文格式 PDF
正文语种 eng
中图分类无机高分子化合物（高聚物）;
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1. Preparation and properties of a fullerene/polysiloxane hybrid from chemically modified fullerene and polymethoxysiloxane [J] . Takahiro Gunji, Kengo Hirama, Satoru Tsukada Journal of Sol-Gel Science and Technology . 2014,第1期

机译：化学改性的富勒烯和聚甲氧基硅氧烷制备的富勒烯/聚硅氧烷杂化物
2. Pentafluorophenyl Transfer Reaction: Preparation of Pentafluorophenyl [60]Fullerene Adducts through Opening of Fullerene Epoxide Moiety with Trispentafluorophenylborane [J] . Sisi Liang, Liang Xu, Zhenshan Jia, The Journal of Organic Chemistry . 2014,第12期

机译：五氟苯基转移反应：通过三五氟苯基硼烷打开富勒烯环氧部分制备五氟苯基[60]富勒烯加合物
3. CuBr/PMDETA-mediated reactions of [60]fullerene with active halides: Preparation of methano[60]fullerene derivatives [J] . Yang H.-T., Tian Z.-Y., Ruan X.-J., European journal of organic chemistry . 2012,第26期

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4. THE PREPARATION OF FULLERENES - A CASE OF INTERDISCIPLINARY RESEARCH [C] . Wolfgang Kratschmer International symposium on fullerenes, nanotubes, and carbon nanoclusters . 2003

机译：富勒烯的制备 - 跨学科研究的情况
5. Synthesis, Separation, and Isolation of [6,6]-Closed Epoxide of Fullerene Using Semi-Preparative High Performance Liquid Chromatography and Preparation of Aqueous Colloidal Suspensions [D] . Ingham, Jesse Raine Lazone. 2020

机译：使用半制备高效液相色谱法[6,6]富勒烯[6,6]氯环氧化丁氧化物的合成，分离和分离及其制备水胶体悬浮液
6. Green and rapid preparation of long-term stable aqueous dispersions of fullerenes and endohedral fullerenes: The pros and cons of an ultrasonic probe [O] . Ivan V. Mikheev, Mariya O. Pirogova, Liliia O. Usoltseva, 2021

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7. Organic Chemistry of Fullerenes. Preparation of Silylmethylated Fullerenes and Their Application to Synthesis of Organic and Inorganic Fullerene Derivatives. [O] . Hideo NAGASHIMA, Kiyokatsu JINNO, Kenji ITOH 1997

机译：富勒烯有机化学。富含甲硅烷基甲基化富勒烯的制备及其在合成有机和无机富勒烯衍生物的应用。

THE PREPARATION OF FULLERENES - A CASE OF INTERDISCIPLINARY RESEARCH

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