Synthesis and Photovoltaic Properties of π-conjugated-C_(60) Ensembles

机译：π-共轭C_（60）集成体的合成及光伏性能

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The tendency to phase segregation in blends of C_(60) derivatives and conjugated polymers has to be optimized to improve both charge photogeneration and transport in photovoltaic devices. In this communication we present two approaches in order to tailor the phase separation in organic films: (ⅰ) the first approach involves the synthesis of functionalized C_(60) derivatives with enhanced solubility; (ⅱ) the second approach is directed to the synthesis of systems containing a π-conjugated moiety antenna covalently linked to the C_(60) unit. Together with the synthesis of these new materials, electrochemical and photophysical investigations have been also carried out. Photovoltaic devices have been fabricated with selected materials.

机译：必须优化C_（60）衍生物和共轭聚合物的共混物中的相偏析趋势，以改善光电器件中的电荷光生和传输。在本交流中，我们提出了两种方法来调整有机膜中的相分离：（ⅰ）第一种方法涉及具有增加的溶解度的官能化C_（60）衍生物的合成；（ⅱ）第二种方法涉及包含共价连接至C_（60）单元的π共轭部分天线的系统的合成。与这些新材料的合成一起，还进行了电化学和光物理研究。光伏器件已经用选定的材料制造。

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来源
《Fullerenes and Nanotubes: The Building Blocks of Next Generation Nanodevices: Fullorenes》|2003年|P.154-163|共10页
会议地点 Paris(FR);Paris(FR);Paris(FR)
作者
Francesco Giacalone; Rafael Gomez; Jose L. Segura; Nazario Martin; Dirk M. Guldi; Chuping Luo; Angela Swartz; Christoph Brabec; N. Serdar Sariciftci;
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Departamento de Quimica Organica, Facultad de Ciencias Quimicas, Universidad Complutense de Madrid, E-28040-Madrid, Spain;

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原文格式 PDF
正文语种 eng
中图分类无机高分子化合物（高聚物）;
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2. Synthesis and photovoltaic properties of acceptor materials based on the dimerization of fullerene C_60 for use in efficient polymer solar cells [J] . Yuta Morinaka, Masahiro Nobori, Michihisa Murata, Chemical Communications . 2013,第35期

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3. Synthesis and Photovoltaic Properties of Polythiophene Derivatives with Side Chains Containing C-60 End Group [J] . He YJ, Hou JH, Tan ZA, Journal of Applied Polymer Science . 2010,第1期

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4. Synthesis and Photovoltaic Properties of π-conjugated-C_(60) Ensembles [C] . Francesco Giacalone, Rafael Gomez, Jose L. Segura, International symposium on fullerenes, nanotubes, and carbon nanoclusters . 2003

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5. Synthesis, characterization and properties of fullerene(60)-4-vinylpyridine copolymer. [D] . Kuo, Changshu Linus. 1998

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6. Improving Photovoltaic Properties of P3HT:IC60BA through the Incorporation of Small Molecules [O] . Binrui Xu, Gopalan Sai-Anand, Anantha-Iyengar Gopalan, 2018

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7. Studies on the Synthesis and Photovoltaic Properties of C60-based Acceptors [O] . 冯娟 2013

机译：C60基受体的合成及其光伏性能的研究

Synthesis and Photovoltaic Properties of π-conjugated-C_(60) Ensembles

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