Stark Spectroscopy Studies of the Langmuir-Blodgett Films of Fluorofullerene C_(60)F_(18)

机译：氟富勒烯C_（60）F_（18）的Langmuir-Blodgett膜的Stark光谱研究

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We present electroabsorption study of C_(60)F_(18) in the Langmuir-Blodgett films and its polymer solution in PMMA matrix. The electroabsorption spectra, which were interpreted in terms of Stark effect showed that some of the excited states of C_(60)F_(18) are characterized by significant changes of the molecular dipole moment, are found responsible for inter- and intramolecular charge transfer (CT). The spectral positions of these intramolecular and intermolecular excitations have been determined. The possibility, that the polar molecules of C_(60)F_(18) (which are theoretically predicted to have a molecular dipole moment of 13 D) can form polar Langmuir-Blodgett films, is discussed.

机译：我们目前在Langmuir-Blodgett膜中的C_（60）F_（18）及其在PMMA基质中的聚合物溶液的电吸收研究。用Stark效应解释的电吸收光谱表明，C_（60）F_（18）的某些激发态的特征是分子偶极矩的显着变化，被认为是分子间和分子内电荷转移的原因（ CT）。这些分子内和分子间激发的光谱位置已经确定。讨论了C_（60）F_（18）的极性分子（理论上预测其分子偶极矩为13 D）可以形成极性Langmuir-Blodgett膜的可能性。

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《Fullerenes and Nanotubes: The Building Blocks of Next Generation Nanodevices: Fullorenes》|2003年|P.440-448|共9页
会议地点 Paris(FR);Paris(FR);Paris(FR)
作者
N.I. Denisenko; S.G. Yudin; S.P.Palto; O.V. Boltalina; L.N. Sidorov;
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Chemistry Department, Moscow State University;

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正文语种 eng
中图分类无机高分子化合物（高聚物）;
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1. Novel facile routes for synthesis and isolation of fluorofullerenes C_(60)F_(18) and C_(60)F_(20) based on commercially available fluorinating reagents [J] . Pavel A.Troshin, Alexey B.Kornev, Alexander S.Peregudov, Journal of Fluorine Chemistry . 2005,第11a12期

机译：基于市售的氟化试剂合成和分离氟富勒烯C_（60）F_（18）和C_（60）F_（20）的新型简便路线
2. Investigation of optical properties of fluorofullerene C_(60)F_(18) single crystals [J] . A.M. Lebedev, K.A. Menshikov, N.Yu. Svechnikov, Nuclear Instruments & Methods in Physics Research. Section A, Accelerators, Spectrometers, Detectors and Associated Equipment . 2007,第1a2期

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3. Electrophilic Aromatic Substitution by the Fluorofullerene C_(60)F_(18) [J] . Adam D.Darwish, Anthony G.Avent, Alaa K.Abdul-Sada Chemistry: A European journal . 2004,第18期

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4. BROMINATED FULLERENES AS PRECURSORS IN THE FORMATION OF FLUOROFULLERENES C_(60)F_(18) LANGMUIR-BLODGETT FILMS [C] . N.I. Denisenko, S.G. Yudin, A.V. Streletskiy, International Symposium on Fullerenes, Nanotubes, and Carbon Nanoclusters, May 12-17, 2002, Philadelphia . 2002

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Stark Spectroscopy Studies of the Langmuir-Blodgett Films of Fluorofullerene C_(60)F_(18)

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