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Adsorption–Desorption-RelatedInterfacial Tension Behaviour in ChemicalFlooding and Its Effect on Oil Recovery

机译:化学驱中吸附-解吸相关的界面张力行为及其对采油率的影响

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This paper reports the investigation of oil–water IFTbehavior when the chromatographic separation of thesurfactant mixture occurs during surfactant/alkalinecorefloods. In this work, surfactant and alkalineconcentrations in the effluent of corefloods andoil–water interfacial tension were determined underdifferent injection strategies. It was found that, in anextended waterflood following an alkaline–surfactantslug injection, surfactant desorbed into the water phase.This desorption of surfactant lasted for a long period ofthe waterflood. Although the concentration of thedesorbed surfactant in the extended waterflood was verylow, an ultra-low oil–water IFT was obtained by using asuitable alkaline concentration. Coreflood results showed that an additional 13% of the initial oil in placewas recovered after the alkaline/surfactant injection bythe synergism of the desorbed surfactant and alkaline.This result indicates that the efficiency and economics ofa chemical flood could be improved by utilizing thedesorbed surfactant during extended waterfloodprocesses.
机译:本文报道了在表面活性剂/碱性岩心驱替期间发生表面活性剂混合物的色谱分离时油水IFT行为的研究。在这项工作中,在不同的注入策略下,确定了岩心驱油流出物中的表面活性剂和碱性浓度以及油水界面张力。结果发现,在注入碱-表面活性剂塞子后的扩展注水中,表面活性剂解吸到水相中。这种表面活性剂的解吸作用持续了很长一段时间。尽管在扩展注水区中解吸的表面活性剂浓度非常低,但通过使用适当的碱浓度可以获得超低油水IFT。 Coreflood结果表明,通过解吸的表面活性剂和碱的协同作用,在注入碱/表面活性剂后,额外的13%的初始油已被采出。该结果表明,在延长的开采期间利用解吸的表面活性剂可以提高化学驱的效率和经济性注水过程。

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