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Structure defects and phase transition in tellurium-doped ZnSe crystals

机译:碲掺杂ZnSe晶体的结构缺陷和相变

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ZnSe crystals grown from the melt by Bridgman method are characterized by the presence of such microstructure defects as pores and solid-phase inclusions, grain boundaries and packing defects of twinning type. Microstructural and X-ray analysis of the grown crystals has shown that optical non-uniformity is mainly due to coherent twinned interlayers related to the phase transition wurtzite (W) -> sphalerite (S) on cooling which is incomplete over (0 0 0 1) W || (1 1 1)S planes. The tellurium dopant affects favorably the optical uniformity and degree of structural perfection of ZnSe(Te) crystals. This is due primarily to the sphalerite structure being completely stabilized during the growth process and the absence of twinning type packing defects (PD). Concentration of tellurium is determined which is sufficient to make complete the W -> S phase transition. direct c 1999 Elsevier Science B.V. All rights reserved.
机译:通过Bridgman方法从熔体中生长的ZnSe晶体的特征是存在诸如孔洞和固相夹杂物,晶界和孪晶型堆积缺陷等微观结构缺陷。对生长晶体的微观结构和X射线分析表明,光学不均匀性主要是由于与相变纤锌矿(W)->闪锌矿(S)冷却相关的相干孪晶中间层,在(0 0 0 1 )W || (1 1 1)S架。碲掺杂剂对ZnSe(Te)晶体的光学均匀性和结构完善程度产生有利影响。这主要是由于闪锌矿结构在生长过程中完全稳定,并且没有孪生型堆积缺陷(PD)。确定足以完成W→S相变的碲浓度。直接c 1999 Elsevier Science B.V.保留所有权利。

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