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BIMETALLIC CLUSTERS: INSIGHTS INTO REACTIONS OF SUBNANOSCALE SURFACES

机译:双金属团簇:对亚尺度尺度表面反应的认识

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摘要

Reactivities of bimetallic clusters can be controlled by varying their composition, making them potentially valuable as catalysts and for use in elucidating the reactivities of such subnanoscale surfaces. A new dual rod laser vaporization source coupled to a fast flow reactor is developed for the study of bimetallic clusters and their reactions. In order to establish the versatility of the technique, the results of studies are presented in which Nb/Al clusters are formed in two plasmas induced by the second harmonic (532 nm photons) of a single Nd:YAG laser and then detected by a quadrupole mass spectrometer. Additional characterization is also performed on V/Al clusters.
机译:可以通过改变其组成来控制双金属簇的反应性,使其成为潜在的有价值的催化剂,并用于阐明这种亚纳米级表面的反应性。开发了一种与快速流动反应器耦合的新型双杆激光汽化源,用于研究双金属簇及其反应。为了建立该技术的多功能性,提出了研究结果,其中在单个Nd:YAG激光器的二次谐波(532 nm光子)诱导的两个等离子体中形成Nb / Al团簇,然后通过四极杆检测质谱仪。还对V / Al群集执行其他表征。

著录项

  • 来源
  • 会议地点 Penn State PA(US);Penn State PA(US)
  • 作者单位

    Department of Chemistry The Pennsylvania State University University Park, PA 16802;

    Department of Chemistry The Pennsylvania State University University Park, PA 16802;

    Department of Chemistry The Pennsylvania State University University Park, PA 16802;

  • 会议组织
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 金属材料;
  • 关键词

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