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Surface tension of molten nickel-chromium alloy

机译:熔融镍铬合金的表面张力

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The surface tension of molten Ni and Ni-Cr (5 and 10 mass fraction) alloys was measured at temperatures of 1773 K ~ 1873 K using an improved sessile drop method with an alumina substrate in an Ar+3%H_2 atmosphere. The surface tension of molten Ni and Ni-Cr (5 and 10 mass fraction) alloys was found to decrease with increasing temperature. On the basis of the experimental data obtained, the surface tension was also theoretically deduced both as functions of concentration and temperature using a model of Butler's equation. The results agreed well with a model for the surface tension. The difference between the experimental data and deduced data may be caused by the measurement error, the assumptions for a surface such as monolayer atom, and the differences in the energy of the Gibbs' free energy of the surface. Chromium was found to segregate on the surface of molten alloys.
机译:在1773 K〜1873 K的温度下,采用改进的无滴落法,在Ar + 3%H_2气氛中,采用氧化铝基底,测量了熔融Ni和Ni-Cr(5和10质量分数)合金的表面张力。发现熔融的Ni和Ni-Cr(5质量分数和10质量分数)合金的表面张力随温度升高而降低。根据获得的实验数据,还使用巴特勒方程模型从理论上推导了表面张力与浓度和温度的关系。结果与表面张力模型非常吻合。实验数据与推导数据之间的差异可能是由测量误差,表面(例如单层原子)的假设以及表面吉布斯自由能的能量差异引起的。发现铬偏析在熔融合金的表面上。

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