首页> 外文会议>IMAPS 2008 - 41st international symposium on microelectronics: bringing together the entire microelectronics supply chain >Comparison of Catalyst Performance for a Direct Methanol Fuel Cell Fabricated in Low Temperature Cofired Ceramics (LTCC)
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Comparison of Catalyst Performance for a Direct Methanol Fuel Cell Fabricated in Low Temperature Cofired Ceramics (LTCC)

机译:低温共烧陶瓷(LTCC)制造的直接甲醇燃料电池催化剂性能的比较

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Integrating a power source, such as a direct methanol fuel cell (DMFC) into a low temperature cofired ceramic (LTCC) based microsystem allows for the next level of microsystem integration. In our LTCC-based DMFC structure, a porous silver tape is used to replace the traditional carbon electrode. Catalysts play a critical role in fuel cell performance. Two catalyst-preparing methods were evaluated, one cofired and one post fired, using platinum and ruthenium resinates for the catalysis source. The cofired anode microstructure demonstrated many whiskers with higher degreed Pt-Ru alloy and Ag while the post fired anode exhibited Ag, lower degreed Pt/Ru alloying and RuO_2. Cyclic voltammetry results show that the cofired catalyst has a better catalyst effect than that of post fired catalyst and both had a better catalysis performance that the catalyst on a standard carbon based anode. These specific catalyst microstructures contributed to the better catalysis effect in the methanol oxidation reaction (MOR) and the oxygen reduction reaction (ORR) respectively.
机译:将电源(例如直接甲醇燃料电池(DMFC))集成到基于低温共烧陶瓷(LTCC)的微系统中,可实现更高级别的微系统集成。在我们基于LTCC的DMFC结构中,多孔银带被用来代替传统的碳电极。催化剂在燃料电池性能中起关键作用。评价了两种催化剂制备方法,一种是共焙烧,另一种是后焙烧,使用铂和钌树脂酸酯作为催化源。共烧阳极微观结构显示出许多晶须具有较高度的Pt-Ru合金和Ag,而后烧阳极具有Ag,较低度的Pt / Ru合金和RuO_2。循环伏安法结果表明,共烧催化剂具有比后烧催化剂更好的催化效果,并且与标准碳基阳极上的催化剂相比,两者均具有更好的催化性能。这些特定的催化剂微观结构分别有助于在甲醇氧化反应(MOR)和氧还原反应(ORR)中更好的催化效果。

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