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Calibration and evaluation of EuTTA fluorescence as active medium for IR-to-visible conversion

机译:用于红外到可见光转换的EuTTA荧光作为活性介质的校准和评估

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Previously, we measured temperature variations employing the spectral power and lifetime of the P-diketonate chelate europium (III) thenoyltrifluoroacetonate (EuTTA). The main goal of our work is to develop a system to convert infrared into visible radiation with EuTTA as the active medium of conversion. Here, we calibrate the fluorescence properties of EuTTA and confirm the reliability of the calibration. We detect black body radiation which serves to change the local temperature of the transducer, with our proposed system. When excited with UV radiation (365 nm), EuTTA fluoresces with its principal emission peak at 615 nm. The changes in spectral power, P_0(T), and mean lifetime, τ(T), of the fluorescence are related with the temperature change induced in the film due to the impinging black body radiation. We present the relative error and temperature differences obtained between the calculated (with calibration) temperature and reference measurements. Furthermore, we demonstrate that incoming radiation, which causes a temperature increase in the transducer (i.e. IR radiation), can be detected through the changes in EuTTA fluorescence parameters.
机译:以前,我们使用对二酮酮螯合euro(III)壬基三氟丙酮酸酯(EuTTA)的光谱功率和寿命来测量温度变化。我们工作的主要目标是开发一种系统,以EuTTA作为转换的活性介质,将红外转换为可见辐射。在这里,我们校准EuTTA的荧光特性,并确认校准的可靠性。通过我们提出的系统,我们检测到黑体辐射,该辐射用于改变传感器的局部温度。当用紫外线(365 nm)激发时,EuTTA发出荧光,其主要发射峰在615 nm。荧光的光谱功率P_0(T)和平均寿命τ(T)的变化与由于撞击黑体辐射而在薄膜中引起的温度变化有关。我们介绍了计算出的(带有校准)温度和参考测量值之间的相对误差和温差。此外,我们证明可以通过EuTTA荧光参数的变化来检测引起换能器温度升高的入射辐射(即IR辐射)。

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