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Preparation and Properties of Asymmetric Porous Aluminium-Oxide Ceramic HollowFibre Membranes

机译:不对称多孔氧化铝陶瓷空心纤维膜的制备与性能

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摘要

Asymmetric porous aluminium-oxide ceramic hollow fibre membranes have been prepared by the phase inversion / sintering technique. The effect of non-solvent such as ethanol, isopropanol and ethylene glycol monomethylether(2-methoxyethanol) on the geometry and performance of hollow fibres was investigated. Morphologies of Al_2O_3 ceramic hollow fibre membranes were characterized using a scanning electron microscope (SEM). The effective porosity and the mechanical strength were determined by Archimedes method, and three point method, respectively. The prepared Al_2O_3 hollow fibre membranes show the asymmetric structure with a finger-like layer and a sponge-like layer. The effective porosity of the prepared hollow fibre membranes exceeds 47%, and the bending strength of the hollow membranes exceeds 63 MPa. The Al_2O_3 hollow fibre membranes with moderate permeation characteristics for gas and pure water are prepared by the introduction of nonsolvent in membrane casting solution. The separation factors of H_2 to N_2 or CO_2 of the hollow fibers with nonsolvent are over 2.0.
机译:通过相转化/烧结技术制备了不对称的多孔氧化铝陶瓷空心纤维膜。研究了非溶剂如乙醇,异丙醇和乙二醇单甲醚(2-甲氧基乙醇)对中空纤维的几何形状和性能的影响。用扫描电子显微镜(SEM)表征Al_2O_3陶瓷中空纤维膜的形貌。有效孔隙率和机械强度分别通过阿基米德法和三点法确定。制备的Al_2O_3中空纤维膜具有不对称结构,具有手指状层和海绵状层。制备的中空纤维膜的有效孔隙率超过47%,中空膜的弯曲强度超过63MPa。通过在膜浇铸液中引入非溶剂,制备出对气体和纯水具有适度渗透特性的Al_2O_3中空纤维膜。非溶剂中空纤维中H_2与N_2或CO_2的分离系数大于2.0。

著录项

  • 来源
  • 会议地点 Guilin(CN)
  • 作者单位

    School of Chemical Engineering, Shandong University of Technology, Zibo 255049, PR China;

    School of Chemical Engineering, Shandong University of Technology, Zibo 255049, PR China;

    School of Chemical Engineering, Shandong University of Technology, Zibo 255049, PR China;

    School of Chemical Engineering, Shandong University of Technology, Zibo 255049, PR China;

  • 会议组织
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    hollow fibre membrane; Al_2O_3; phase inversion; non-solvent;

    机译:中空纤维膜Al_2O_3;相位反转非溶剂;

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