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Measurement of Adhesion Energy of Electrospun Polymer Membranes Using a Shaft-loaded Blister Test

机译:使用轴载吸塑试验测量电纺聚合物膜的粘附能

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This study aims to examine the adhesion work of electrospun polymer nano- and micro-fibers.The adhesion energy at the interface of electrospun membrane and a rigid substrate is characterized by a shaft-loaded blister test (SLBT).By controlling the processing parameters,polyvinylidene fluoride (PVDF) fibrous membranes are prepared with fiber diameters ranging from 201 ± 86 nm to 2,724 ± 587 nm.The adhesion energy between electrospun membrane and rigid substrate increases from 8.1 ± 0.7 mJ/m2 to 258.8 ± 43.5 mJ/m2 by use of smaller fiber diameters.Adhesion energies between electrospun PVDF membranes and SiC substrates made of different grain sizes are evaluated.Fibrous membrane produces an adhesion energy as high as 420.1 ± 62.9 mJ/m2 in contact with SiC substrate with a 68 μm grit size.The SLBT methodology is extended to understand the adhesion energy between electrospun membranes.The increase in adhesion work is attributed to an increased area between fiber delaminated surfaces and surface asperities.
机译:这项研究的目的是检查电纺聚合物纳米纤维和微纤维的粘合性能。电纺膜与刚性基材之间的界面处的粘合能通过轴载起泡试验(SLBT)进行表征。通过控制加工参数,制备的聚偏二氟乙烯(PVDF)纤维膜的纤维直径范围为201±86 nm至2,724±587 nm。通过使用,电纺膜与刚性基材之间的粘合能从8.1±0.7 mJ / m2增加到258.8±43.5 mJ / m2评估了电纺PVDF膜与不同粒径的SiC衬底之间的粘合能,与粒度为68μm的SiC衬底接触时,纤维膜产生的粘合能高达420.1±62.9 mJ / m2。扩展了SLBT方法以了解电纺膜之间的粘合能。粘合功的增加归因于纤维分层表面和表面之间的面积增加。面对凹凸不平。

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