Aluminum bisphenoxides: Promising challengers for a catalyzed copolymerization of cyclohexene oxide with CO_2

机译：双酚铝：环氧丙烷与CO_2催化共聚的有挑战性的挑战者

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Reacting triethyl aluminum and diethyl aluminum chloride with the chelating bisphenol ligands mdtbpH2 and mmcpH2 [mmcpH2: 2,2′-methylenebis(4-methyl-6-(1-methyl-cyclohexyl)phenol); mdtbpH2: 2,2′-methylenebis(4,6-di-tert-butyl-phenol)] afforded monomeric and dimeric aluminum bisphenoxides with reactive Al-Cl and Al-C_2H_5 moieties. We present here the X-ray structure determination of some of the isolated compounds as well as the preliminary catalytic tests in copolymerization reactions with cyclohexene oxide and carbon dioxide.

机译：使三乙基铝和二乙基氯化铝与螯合的双酚配体mdtbpH2和mmcpH2 [mmcpH2：2,2'-亚甲基双（4-甲基-6-（1-甲基-环己基）苯酚）反应； mdtbpH2：2,2'-亚甲基双（4,6-二叔丁基苯酚）]提供具有反应性Al-Cl和Al-C_2H_5部分的单体和二聚双酚铝。我们在这里介绍一些分离出的化合物的X射线结构测定，以及与环己烯氧化物和二氧化碳共聚反应的初步催化试验。

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来源
《International Conference on Carbon Dioxide Utilization; 20050620-23; Oslo(NO)》|2005年|151-161|共11页
会议地点 Oslo(NO)
作者
Thomas A. Zevaco; Jakub Sypien; Annette Janssen; Olaf Walter; Eckhard Dinjus;
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作者单位

Forschungszentrum Karlsruhe GmbH, Institut fuer Technische Chemie-Chemisch-Physikalische Verfahren, Postfach 3640, 76021 Karlsruhe, Germany;

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原文格式 PDF
正文语种 eng
中图分类二氧化碳的生产;
关键词
aluminum bisphenoxides; cyclohexene oxide; aliphatic polycarbonate; IR spectroscopy; NMR spectroscopy; GPC; carbon dioxide; Co-catalyst;

机译：双酚铝;氧化环己烯脂族聚碳酸酯；红外光谱NMR光谱； GPC；二氧化碳;助催化剂;

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专利

1. Aluminum bisphenoxides:Promising challengers for a catalyzed copolymerization of cyclohexene oxide with CO_2 [J] . Thomas A.Zevaco, Jakub Sypien, Annette Janssen, Catalysis Today . 2006,第1a4期

机译：双酚铝：环氧丙烷与CO_2催化共聚的有挑战性的挑战者
2. Alternating Copolymerization of Cyclohexene Oxide and CO_2 Catalyzed by Zinc Complexes with New 3-Amino-2-cyanoimidoacrylate Ligands [J] . Mario Kroger, Cristina Folli, Olaf Walter, Advanced synthesis & catalysis . 2005,第10期

机译：新型3-氨基-2-氰基亚氨基丙烯酸酯配体与锌配合物催化环氧乙烷与CO_2的交替共聚
3. Structural Characterization of Tridentate N-Heterocyclic Carbene Titanium(IV) Benzyloxide, Silyloxide, Acetate, and Azide Complexes and Assessment of Their Efficacies for Catalyzing the Copolymerization of Cyclohexene Oxide with CO2 [J] . Quadri Coralie C., Lalrempuia Ralte, Hessevik Julie, Organometallics . 2017,第22期

机译：三季氮杂环钛（IV）苄氧化物，甲硅烷基甲醚，乙酸酯和叠氮化物复合物的结构表征及其催化环己烯与CO2共聚的疗效评估
4. Aluminum bisphenoxides: Promising challengers for a catalyzed copolymerization of cyclohexene oxide with CO_2 [C] . Thomas A. Zevaco, Jakub Sypien, Annette Janssen, International Conference on Carbon Dioxide Utilization . 2006

机译：双酚氧化铝：具有CO_2催化环己烯的共聚的承诺挑战者
5. Cobalt and chromium salen complexes catalyzed copolymerization of CO2 and epoxides: The scope of epoxides. [D] . Chung, Wan-Chun. 2015

机译：钴和铬塞伦络合物催化CO2和环氧化物的共聚：环氧化物的范围。
6. Alternating copolymerization of carbon dioxide and cyclohexene oxide catalyzed by salen CoIII(acetate) complexes [O] . Yongsheng Niu, Hongchun Li -1

机译：Salen CoIII（乙酸盐）配合物催化的二氧化碳和环己烯氧化物的交替共聚
7. Alternating Copolymerization of Carbon Dioxide with Cyclohexene Oxide Catalyzed by a Novel Catalyst [O] . Lidan Fan, Gang Qin, Xinxin Cao, 2016

机译：新型催化剂催化二氧化碳与环己烯氧化物的交替共聚反应
8. Reaction of Cyclohexene with Iodosylbenzene Catalyzed by Non-Porphyrin Complexesof Iron(III) and Aluminum(III). Newly Discovered Products and a New Mechanistic Proposal [R] . Yang, Y., Diederich, F., Valentine, J. S. 1990

机译：铁（III）和铝（III）非卟啉配合物催化环己烯与碘代苯的反应。新发现的产品和新的机械方案

Aluminum bisphenoxides: Promising challengers for a catalyzed copolymerization of cyclohexene oxide with CO_2

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