首页> 外文会议>International Conference on Deformation, Yield and Fracture of Polymers; 20000410-20040413; Cambridge; GB >WIDE- AND SMALL-ANGLE X-RAY SCATTERING STUDIES ON THE DEFORMATION BEHAVIOUR OF POLY(ETHYLENE TEREPHTHALATE)
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WIDE- AND SMALL-ANGLE X-RAY SCATTERING STUDIES ON THE DEFORMATION BEHAVIOUR OF POLY(ETHYLENE TEREPHTHALATE)

机译:聚乙烯对苯二甲酸酯的变形行为的广角和小角X射线散射研究

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In this study the microscopic deformation behaviour of amorphous PET during uni-axial tensile tests at room temperature was investigated by in-situ wide- and small-angle X-ray scattering using synchrotron radiation. WAXD patterns of deformed PET show a highly orientated amorphous halo and no significant crystallization was found. SAXS patterns of the slowest drawn samples show typical craze like patterns, which finally evolve in elliptically shaped patterns, indicating micro voiding. At higher draw rates the formation of fibrils is not observed and the material directly cavitates. This micro voiding phenomenon causes whitening of the deformed PET.
机译:在这项研究中,通过使用同步加速器辐射的原位广角和小角X射线散射研究了室温下单轴拉伸试验中非晶PET的微观变形行为。变形PET的WAXD模式显示出高度取向的无定形晕,并且未发现明显的结晶。绘制速度最慢的样本的SAXS模式显示出典型的开裂状模式,最终演变为椭圆形模式,表明存在微空隙。在较高的拉伸速率下,未观察到原纤维的形成,并且材料直接空化。这种微空隙现象导致变形的PET变白。

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