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Analytical chemistry: feeding the environmental revolution?

机译:分析化学:推动环境革命吗?

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Abstract: There can be no question in anyone's mind that our ability to analyze the structure and composition of materials in all media has grown in amazingly exponential ways in the last several decades. Our detection limits have gone from micrograms to the subpicogram level. A millimeter-sized sample presented a challenge in 1950; but today we look at submicron units, in fact, at single atoms resolved in analytical electron microscopes in an almost routine manner. Analysis time has changed from hours or sometimes even days for a complete qualitative and quantitative analysis on a sample to modern capabilities which include real-time spectroscopy on in situ experiments which give us data on molecular dynamics in the femtosecond time regime. Trace analysis, the detection and determination of impossibly tiny quantities of elements and molecules in increasingly complex matrices, is readily accomplished today. These are exactly the types of samples usually involved in environmental analysis. Yet, there is a tendency among some groups to view analytical advances as a negative factor in environmental studies because the ability to measure extremely small quantities can focus regulators on placing restrictions on materials not previously detectable. If so, that is a rare instance where increased knowledge can be considered a setback.!22
机译:摘要:毫无疑问,在过去的几十年中,我们分析所有媒体中材料的结构和成分的能力以惊人的指数方式增长。我们的检测极限已从微克提高到亚皮克级。毫米大小的样本在1950年提出了挑战。但是今天,我们实际上是在分析电子显微镜中以几乎常规方式解析的单个原子,来研究亚微米单位。分析时间已经从数小时甚至是数天,甚至可以从一个样品上完成一个完整的定性和定量分析,到现代化的功能,包括在原位实验中进行实时光谱分析,从而为我们提供了飞秒时间范围内分子动力学的数据。如今,痕量分析,日益复杂的基质中微量元素和分子的检测和测定已经很容易完成。这些正是环境分析中通常涉及的样本类型。但是,有些团体倾向于将分析的进展视为环境研究中的不利因素,因为测量极少量物质的能力可以使监管者将重点放在对以前无法检测到的材料进行限制。如果是这样,那是很少见的情况,在这种情况下,增加的知识可被视为挫折。

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