Catalysis by Metal Ions of the Reaction of Ozone andChloride Ion in Acid Solutions

机译：金属离子在酸性溶液中催化臭氧与氯离子反应

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It has been found out that VO2+, Fe3+, Co2+ ions are catalysts of thernreaction between ozone and chloride ion in acid medium, Al3+, Cr3+,rnCr2O72-, Ni2+, Cu2+, Zn2+, Ce3+ ions do not have catalytic effect. Thernrate of Cb emission in the O3+Cl- reaction has been studied as arnfunction of H+, VO2+, Fe3+, Co2+ concentrations in the reaction solution.rnThe scheme of the catalytic reaction has been proposed, that explainsrnthe experimental data on catalytic action of H+, VO2+, Fe3+, Co2+ ions.rnThe numerical values of the constants of the scheme stages have beenrndetermined.

机译：已经发现，VO 2+，Fe 3+，Co 2+离子是在酸性介质中臭氧与氯离子之间的反应的催化剂，Al 3+，Cr 3+，rnCr 2 O 72-，Ni 2+，Cu 2+，Zn 2+，Ce 3+离子没有催化作用。以反应液中H +，VO2 +，Fe3 +，Co2 +浓度的函数为函数，研究了O3 + Cl-反应中Cb的释放速率。提出了催化反应的方案，解释了H +催化作用的实验数据， VO2 +，Fe3 +，Co2 +离子。rn已经确定了方案阶段常数的数值。

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来源
《International Ozone Association 16th world congress: abstracts and full papers of oral presentations》|2003年|1-12|共12页
会议地点 Las Vegas NV(US)
作者
Kuskov I.V.; Levanov A.V.; Koyaydarova K.B.; Zosimov A.V.; Antipenko E.E.; Lunin V.V.;
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作者单位

Moscow State University, Chemistry Department, Moscow 119992, RussiarnE-mail: kuskov@kge.msu.ru;

Moscow State University, Chemistry Department, Moscow 119992, Russia;

Moscow State University, Chemistry Department, Moscow 119992, Russia;

Moscow State University, Chemistry Department, Moscow 119992, Russia;

Moscow State University, Chemistry Department, Moscow 119992, Russia;

Moscow State University, Chemistry Department, Moscow 119992, Russia;

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原文格式 PDF
正文语种 eng
中图分类
关键词
Ozone; Chloride Ion; Catalysis by Metal Ions; Kinetics; Mechanism;

机译：臭氧;氯离子;金属离子催化;动力学;机理;

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Catalysis by Metal Ions of the Reaction of Ozone andChloride Ion in Acid Solutions

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