首页> 外文会议>International Symposium on Eco-Materials Processing amp; Design; 20060108-11; Chengdu(CN) >Properties of Coating Films Synthesized from Nano Colloidal Silica and Alkoxy Silanes
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Properties of Coating Films Synthesized from Nano Colloidal Silica and Alkoxy Silanes

机译:纳米胶体和烷氧基硅烷合成的涂膜性能

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Colloidal silica/silane sol solutions were prepared in variation with the ratio of silane to colloidal silica. Such sol solutions were synthesized from colloidal silica/tetramethoxysilane (TMOS)/methyltrimethoxysilane(MTMS). Sol solutions were prepared by sol-gel reaction through two step reactions. To understand their physical and chemical properties, dip coating of sol solutions was performed on the glass substrates. Contact angle and thickness of coating films increased with increasing the amount of MTMS. The surface free energy of coating films decreased with increasing amount of MTMS. Coating films were stable until 550℃. Thermal degradation temperature of coating films decreased with increasing amount of MTMS. Plastic hardness decreased with increasing amount of MTMS. Elastic portion increased with increasing amount of MTMS.
机译:胶体二氧化硅/硅烷溶胶溶液的制备随硅烷与胶体二氧化硅的比例变化而变化。这种溶胶溶液是由胶体二氧化硅/四甲氧基硅烷(TMOS)/甲基三甲氧基硅烷(MTMS)合成的。通过两步反应,通过溶胶-凝胶反应制备溶胶溶液。为了理解它们的物理和化学性质,在玻璃基板上进行了溶胶溶液的浸涂。接触角和涂膜厚度随着MTMS用量的增加而增加。涂膜的表面自由能随着MTMS的增加而降低。涂膜稳定到550℃。涂膜的热降解温度随​​着MTMS的增加而降低。塑性硬度随着MTMS含量的增加而降低。弹性部分随着MTMS数量的增加而增加。

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