ELECTROCHEMICAL SYNTHESIS OF INORGANIC AND ORGANIC COMPOUNDS WITH BORON-DOPED DIAMOND ELECTRODES

机译：掺硼金刚石电极的无机和有机化合物的电化学合成

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The Boron-Doped Diamond (BDD) electrode is a new electrode material with high stability, even at high anodic potential. Furthermore BDD is not prone to fouling. Due to these properties, BDD can provide new opportunities in electrochemical synthesis of organic and inorganic compounds. Two examples are given to demonstrate the feasibility of electroorganic synthesis on BDD anodes. The first example is the oxidation of phenol to benzoquinone, an important intermediate in fine organic synthesis. The second example is the oxidation of 3-methylpiridine to nicotinic acid, an important pharmaceutical intermediate. Two strong inorganic oxidants have been prepared using BDD anodes: the Ag(I) to Ag(Ⅱ) oxidation and the oxidation of sulfate to peroxodisulfate.

机译：硼掺杂金刚石（BDD）电极是一种即使在高阳极电位下也具有高稳定性的新型电极材料。此外，BDD不容易结垢。由于这些特性，BDD可以为有机和无机化合物的电化学合成提供新的机会。给出了两个例子来证明在BDD阳极上进行有机合成的可行性。第一个例子是苯酚氧化为苯醌，这是精细有机合成中的重要中间体。第二个例子是3-甲基吡啶被氧化为烟酸，一种重要的药物中间体。使用BDD阳极制备了两种强无机氧化剂：Ag（I）到Ag（Ⅱ）的氧化和硫酸盐到过二硫酸盐的氧化。

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来源
《International Symposium on Energy and Electrochemical Processes for a Cleaner Environment, 2001, San Francisco, CA》|2001年|p.87-96|共10页
会议地点 San Francisco CA(US);San Francisco CA(US)
作者
P.-A. Michaud; Ch. Comninellis; W. Haenn; A. Perret; J. Iniesta; M. Fryda; L.Schaefer;
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Institute of Chemical Engineering Swiss Federal Institute of Technology, CH-1015 Lausanne, Switzerland;

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正文语种 eng
中图分类环境污染及其防治;
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1. Electrochemical oxidation of organic compounds on boron-doped diamond electrodes [J] . Lochynski Pawel, Dittmar Thomas, Worch Eckhard, Przemysl Chemiczny . 2015,第12期

机译：硼掺杂金刚石电极上有机化合物的电化学氧化
2. Electrochemical oxidation of phenol at boron-doped diamond electrode. Application to electro-organic synthesis and wastewater treatment [J] . Marco Panizza, Giacomo Cerisola, Pierre-Alain Michaud, Annali di Chimica: Journal of Analytical and Environmental Chemistry . 2002,第10期

机译：掺硼金刚石电极上苯酚的电化学氧化。在有机合成和废水处理中的应用
3. Electrochemical oxidation of 3-methylpyridine at a boron-doped diamond electrode: application to electroorganic synthesis and wastewater treatment [J] . J. Iniesta, P. A. Michaud, M. Panizza, Electrochemistry communications . 2001,第7期

机译：硼掺杂金刚石电极上3-甲基吡啶的电化学氧化：在有机合成和废水处理中的应用
4. Electrochemical systhesis of inorganic and organic compounds with boron-doped diamond electrodes [C] . P.-A. Michaud, Ch. Comninellis, W. Haenn, International symposium on energy and electrochemical processes for a cleaner environment . 2001

机译：具有硼掺杂金刚石电极的无机和有机化合物的电化学合成
5. Electrochemical oxidation of phenol in simulated petrochemical wastewaters using boron-doped diamond electrodes: Investigation of effect of ammonia, carbon nitride and sulfur presence. [D] . Dalhat, Mu'azu Nuhu. 2010

机译：使用掺硼金刚石电极在模拟石化废水中苯酚的电化学氧化：研究氨，氮化碳和硫的存在的影响。
6. High-Temperature Oxidation of Heavy Boron-Doped Diamond Electrodes: Microstructural and Electrochemical Performance Modification [O] . Jacek Ryl, Mateusz Cieslik, Artur Zielinski, 2020

机译：重硼掺杂金刚石电极的高温氧化：微观结构和电化学性能的修改。
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机译：利用硼掺杂金刚石电极的电化学减少CO _{2 ：朝向具有大量碳原子的生产化合物}
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机译：插层化合物和新型无机氟化合物的合成。

ELECTROCHEMICAL SYNTHESIS OF INORGANIC AND ORGANIC COMPOUNDS WITH BORON-DOPED DIAMOND ELECTRODES

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