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Thermal Evolution of Fe_(65)Ni_(20)Nb_6B_9 Nanocrystalline Metastable Alloy

机译:Fe_(65)Ni_(20)Nb_6B_9纳米晶亚稳合金的热演化

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The alloy Fe_(65)Ni_(20)Nb_6B_9 was obtained from the elemental constituents in a high-energy planetary ball mill and was studied by ~(57)Fe Mossbauer effect spectroscopy, Mossbauer thermal scans and X-ray diffraction. The as prepared nanocrystalline alloy consisted primarily of metastable bcc α-Fe(Ni) nanocrystals (57 nm average size) and small amounts of γ-(Fe,Ni) with Ni concentration of about 58%. Up to about 693 K only defect recovery is inferred. Between 693 and 873 K the α-phase transformed gradually into the fcc γ-phase, whose starting Ni concentration decreased continuously with increasing temperature, reaching a final value which was below 32 at%.
机译:Fe_(65)Ni_(20)Nb_6B_9合金是从高能行星式球磨机中的元素成分获得的,并通过〜(57)Fe Mossbauer效应光谱,Mossbauer热扫描和X射线衍射进行了研究。所制备的纳米晶合金主要由亚稳态的bccα-Fe(Ni)纳米晶体(平均尺寸为57 nm)和少量的γ-(Fe,Ni)组成,其中Ni的浓度约为58%。最多只能推断到693K。在693至873 K之间,α相逐渐转变为fccγ相,其起始Ni浓度随温度升高而连续降低,最终值低于32 at%。

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