CHAIN-GROWTH POLYCONDENSATIONS-A NEW TOOL IN ENGINEERING OF CONJUGATED POLYMERS

机译：链增长缩聚-共轭聚合物工程中的一种新工具

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@@We would like to present a new paradigm in the engineering of nanostructured hybrids between conjugated polymer and inorganic materials via surface-initiated catalyst-transfer polycondensations (SI-KCTPs) based on Kumada1,2 and Suzuki3 chaingrowth polycondensations. In particular, grafting of regioregular poly(3-alkylthiophenes), P3ATs, from planar surfaces1 and from particles (submicron and nanoscale) was developed and will be presented here.2 Surface-initiated polymerization (SIP) from particles is a powerful tool in engineering of novel polymerbased hybrid materials. Polymers densely grafted to surfaces may exhibit novel and useful properties because of chain-overstretching caused by excluded volume interactions.

机译：@@我们想通过基于Kumada1,2和Suzuki3 Chaingrowth缩聚的表面引发的催化剂转移缩聚（SI-KCTP），提出共轭聚合物与无机材料之间的纳米结构杂化体工程学的新范例。特别是，已开发并在本文中介绍了从平面1和颗粒（亚微米和纳米级）接枝规则型聚（3-烷基噻吩）P3AT的方法。2颗粒的表面引发聚合（SIP）是工程上的强大工具新型基于聚合物的混合材料。紧密接枝到表面的聚合物可能会表现出新颖而有用的特性，这是由于排除的体积相互作用导致链过度拉伸。

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《International symposium on polymer chemistry : Preprints.》|2010年|p.123-124|共2页
会议地点 Suzhou(CN);Suzhou(CN)
作者
Anton Kiriv; Volodymyr Senkovskyy; Roman Tkachov;
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作者单位

Leibniz-Institut fur Polymerforschung Dresden e.V., Hohe Strafie 6, 01069 Dresden, Germany;

Leibniz-Institut fur Polymerforschung Dresden e.V., Hohe Strafie 6, 01069 Dresden, Germany;

Leibniz-Institut fur Polymerforschung Dresden e.V., Hohe Strafie 6, 01069 Dresden, Germany;

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原文格式 PDF
正文语种 eng
中图分类高分子化合物工业（高聚物工业）;高分子化合物工业（高聚物工业）;
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1. Development of a universal chain-growth polymerization protocol of conjugated polymers: Toward a variety of all-conjugated block-copolymers [J] . Verswyvel M., Verstappen P., De Cremer L., Journal of Polymer Science, Part A. Polymer Chemistry . 2011,第24期

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4. CHAIN-GROWTH POLYCONDENSATIONS-A NEW TOOL IN ENGINEERING OF CONJUGATED POLYMERS [C] . Anton Kiriv, Volodymyr Senkovskyy, Roman Tkachov International symposium on polymer chemistry . 2010

机译：链生长缩聚 - 共轭聚合物工程中的一种新工具
5. Hit-to-Lead” Approaches to Engineering Properties in Conjugated Polymer Semiconductors The alternating copolymer architecture of contemporary π-conjugated polymer semiconductors (PSCs) affords remarkable control over materials properties through combinati [D] . Lopez-Ponnada, Emma V. 2019

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7. Development of a Universal Chain-Growth Polymerization Protocol of Conjugated Polymers: Toward a Variety of All-Conjugated Block-Copolymers [O] . Verswyvel Michiel, Verstappen Pieter, De Cremer Lieven, 2011

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CHAIN-GROWTH POLYCONDENSATIONS-A NEW TOOL IN ENGINEERING OF CONJUGATED POLYMERS

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