HYDROGEN BONDING, MISCIBILITY, AND THERMAL BEHAVIOR OF BIODEGRADABLE POLYMER BLENDS OF POLY(3-HYDROXYBUTYRATE) AND POLY(4-VINYLPHENOL)

机译：聚（3-羟基丁酸酯）和聚（4-乙烯基苯酚）的生物可降解聚合物共混物的氢键合，混溶性和热行为

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@@The hydrogen bonding interactions, miscibility, and crystallinity of biodegradable polymer poly(3hydroxybutyrate) (PHB) blended with poly(4vinylphenol) (PVPh) were studied on the casting films as a function of the blend composition wpvph and temperature by using Fourier-transform infrared (FTIR) spectroscopy, differential scanning calorimetry (DSC), and wide angle X-ray diffraction (WAXD). Over the whole composition range of PHB/PVPh blends, all DSC thermograms apparently exhibit a single T_g, and these values increase with wrvn, indicating that the PHB is miscible with PVPh in the melt state or the amorphous part of PHB is miscible with PVPh when PHB is crystallized in the blend. The intermolecular hydrogen bondings between the C=O groups of PHB and the OH groups of PVPh (designed as inter) were explored not only in C=O stretching vibration region but also in OH stretching vibration region. For PHB, the intramolecular hydrogen bonding interactions between the C=O groups and CH_3 groups of PHB (designed as intra) exists in lamellar structure of crystal part. The competing hydrogen bonding interactions between intra and inter is a crucial physical factor underlying the basic physics of the blends with respect to ordering via crystallization, miscibility, and even phase separation.

机译：通过使用傅立叶分析法研究了可生物降解的聚合物聚（3-羟基丁酸酯）（PHB）与聚（4-乙烯基苯酚）（PVPh）混合时的氢键相互作用，可混溶性和结晶度，其与混合组分wpvph和温度的关系。变换红外（FTIR）光谱，差示扫描量热法（DSC）和广角X射线衍射（WAXD）。在PHB / PVPh混合物的整个组成范围内，所有DSC热谱图都显示出一个单一的T_g，并且这些值随wrvn的增加而增加，表明PHB在熔融状态下可与PVPh混溶，或当PHB的无定形部分与PVPh可混溶。 PHB在混合物中结晶。不仅在C = O拉伸振动区域内，而且在OH拉伸振动区域内，都探索了PHB的C = O基团与PVPh的OH基之间的分子间氢键（设计为间）。对于PHB，PHB的C = O基团和CH_3基团（设计为内部）之间的分子内氢键相互作用存在于晶体部分的层状结构中。内部和内部之间竞争性的氢键相互作用是决定共混物基本结晶的基本物理因素，这些因素涉及结晶，可混溶甚至相分离的顺序。

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《International symposium on polymer physics : Preprints.》|2010年|p.273-274|共2页
会议地点 Jinan(CN);Jinan(CN)
作者
Lonehai Guo; Harutni Sato; Takeji Hashimoto; Yukihiro Ozaki;
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作者单位

Department of Chemistry, School of Science and Technology, Kwansei-Gakuin University, Gakuen 2-1, Sanda 669-1337, Japan;

Department of Chemistry, School of Science and Technology, Kwansei-Gakuin University, Gakuen 2-1, Sanda 669-1337, Japan;

Department of Chemistry, School of Science and Technology, Kwansei-Gakuin University, Gakuen 2-1, Sanda 669-1337, Japan;

Department of Chemistry, School of Science and Technology, Kwansei-Gakuin University, Gakuen 2-1, Sanda 669-1337, Japan;

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正文语种 eng
中图分类高分子化学（高聚物）;高分子化学（高聚物）;
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1. FTIR Study on Hydrogen-Bonding Interactions in Biodegradable Polymer Blends of Poly(3-hydroxybutyrate) and Poly(4-vinylphenol) [J] . Guo LH, Sato H, Hashimoto T, Macromolecules . 2010,第8期

机译：FTIR研究聚（3-羟基丁酸酯）与聚（4-乙烯基苯酚）的可生物降解聚合物共混物中的氢键相互作用
2. Thermally induced exchanges of hydrogen bonding interactions and their effects on phase structures of poly(3-hydroxybutyrate) and poly(4-vinylphenol) blends [J] . Guo L., Sato H., Hashimoto T., Macromolecules . 2011,第7期

机译：氢键相互作用的热诱导交换及其对聚3-羟基丁酸酯和聚4-乙烯基苯酚共混物的相结构的影响
3. Miscibility enhancement through hydrogen bonding interaction of biodegradable poly(3-hydroxybutyrate) blending with poly(styrene-co-vinyl phenol) copolymer [J] . Kuo S.-W., Liu W.-C. Journal of Applied Polymer Science . 2011,第1期

机译：通过可生物降解的聚（3-羟基丁酸酯）与聚（苯乙烯-共-乙烯基苯酚）共聚物共混的氢键相互作用增强混溶性
4. HYDROGEN BONDING, MISCIBILITY, AND THERMAL BEHAVIOR OF BIODEGRADABLE POLYMER BLENDS OF POLY(3-HYDROXYBUTYRATE) AND POLY(4-VINYLPHENOL) [C] . Lonehai Guo, Harutni Sato, Takeji Hashimoto, International symposium on polymer physics . 2010

机译：聚（3-羟丁酯）和聚（4-乙烯基苯酚）的可生物降解聚合物共混物的氢键，混溶性和热行为
5. Biodegradable polymer blends of poly lactic acid and poly ester amide [D] . Labrecque, Roger Lucien, Jr. 1997

机译：聚乳酸和聚酯酰胺的可生物降解聚合物共混物
6. Effect of Selected Commercial Plasticizers on Mechanical Thermal and Morphological Properties of Poly(3-hydroxybutyrate)/Poly(lactic acid)/Plasticizer Biodegradable Blends for Three-Dimensional (3D) Print [O] . Přemysl Menčík, Radek Přikryl, Ivana Stehnová, 2018

机译：选定的市售增塑剂对三维（3D）打印用聚（3-羟基丁酸酯）/聚乳酸/增塑剂可生物降解共混物的机械热学和形态学性能的影响
7. Studies on Hydrogen Bonding Interactions and Crystal Structures of Poly(3-hydroxybutyrate) and Its Blends with Poly(4-vinylphenol) by Infrared Spectroscopy and Time-Resolved Small-Angle X-ray Scattering and Wide-Angle X-ray Diffraction [O] . 郭隆海, Longhai Guo 2012

机译：用红外光谱和时间分辨小角X射线散射和广角X射线衍射研究聚（3-羟基丁酸酯）及其与聚（4-乙烯基苯酚）共混物的氢键相互作用和晶体结构

HYDROGEN BONDING, MISCIBILITY, AND THERMAL BEHAVIOR OF BIODEGRADABLE POLYMER BLENDS OF POLY(3-HYDROXYBUTYRATE) AND POLY(4-VINYLPHENOL)

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