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Chapter 21 Tailoring Adsorption-Desorption Properties of Hydroamination Catalysts with Ionic Liquids

机译：第21章调整离子液体对加氢催化剂的吸附-解吸性能

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Highly active and selective homogeneous catalysts are known for atom efficient syntheses of aromatic and aliphatic amines from alkenes and alkynes. We have shown that catalytically active metal cations (such as Zn~(2+)) can be incorporated in zeolites and display a higher activity due to the simultaneous presence of Lewis acid sites and Bronsted acidic hydroxyl groups. Surprisingly high catalytic activities were also observed for molecular catalysts in two phase systems where the catalyst was dissolved in an ionic liquid. The high activity is caused by a high solubility of the reactants in the catalyst phase whereas the products are hardly soluble. Here we report on well-tailored catalysts combining both approaches.

机译：众所周知，高活性和选择性的均相催化剂可有效地从烯烃和炔烃中高效合成芳族和脂族胺。我们已经表明，具有催化活性的金属阳离子（例如Zn〜（2+））可以掺入沸石中，并且由于路易斯酸位和布朗斯台德酸性羟基的同时存在而显示出更高的活性。在两相体系中，将分子催化剂溶解在离子液体中，也观察到了很高的催化活性。高活性归因于反应物在催化剂相中的高溶解度，而产物几乎不溶。在这里，我们报告结合两种方法的量身定制的催化剂。

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《Ionic liquids in organic synthesis》|2004年|267-280|共14页
会议地点 Philadelphia PA(US);Philadelphia PA(US)
作者
Oriol Jimenez; Thomas E. Muellet; Johannes A. Lercher;
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Lehrstuhl II fuer Technische Chemie, Technische Universitaet Muenchen, Lichtenbergstrasse 4, 85747 Garching, Germany;

Lehrstuhl II fuer Technische Chemie, Technische Universitaet Muenchen, Lichtenbergstrasse 4, 85747 Garching, Germany Faculty of Science, Department of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore 117543;

Lehrstuhl II fuer Technische Chemie, Technische Universitaet Muenchen, Lichtenbergstrasse 4, 85747 Garching, Germany;

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正文语种 eng
中图分类基本有机化学工业;
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1. Tailoring ionic liquid catalysts: structure, acidity and catalytic activity of protonic ionic liquids based on anionic clusters, [(HSO4)(H2SO4)_X]~-(x = 0,1, or 2) [J] . Karolina Matuszek, Anna Chrobok, Fergal Coleman Green chemistry . 2014,第7期

机译：定制离子液体催化剂：基于阴离子簇[[HSO4）（H2SO4）_X]〜-（x = 0,1或2）的质子离子液体的结构，酸度和催化活性
2. Markownikoff and anti-Markownikoff hydroamination with palladium catalysts immobilized in thin films of silica supported ionic liquids [J] . Oriol Jimenez, Thomas E. Mueller, Carsten Sievers, Chemical Communications . 2006,第28期

机译：Markownikoff和Markownikoff抗加氢胺化反应，其钯催化剂固定在二氧化硅负载的离子液体薄膜中
3. Integration of phosphine ligands and ionic liquids both in structure and properties - a new strategy for separation, recovery, and recycling of homogeneous catalyst (vol 21, pg 3583, 2019) [J] . Jin Xin, Feng Jianying, Song Hongbing, Green chemistry . 2019,第22期

机译：膦配体和离子液体的整合结构和性质 - 一种新的分离，回收和均相催化剂的新策略（Vol 21，PG 3583,2019）
4. Chapter 7 Transition Metal Complexes in Imidazolium Ionic Liquids as Recoverable and Reusable Homogeneous Catalysts [C] . Hermenegildo Garcia, Esther Carbonell Ionic liquids in organic synthesis . 2004

机译：第7章咪唑鎓离子液体中的过渡金属络合物是可回收和可重复使用的均相催化剂
5. Ionic liquids as lubricants of metal -polymer contacts. Preparation and properties of the first dispersions of ionic liquids and nanoparticles in polymers [D] . Sanes Molina, Jose 2008

机译：离子液体作为金属-聚合物触点的润滑剂。离子液体和纳米粒子在聚合物中的第一分散液的制备和性能
6. Correction: Zielinski W. et al. Ionic Liquids as Solvents for Rhodium and Platinum Catalysts Used in Hydrosilylation Reaction. Molecules 2016 21 1115 [O] . Witold Zielinski, Rafal Kukawka, Hieronim Maciejewski, 2017

机译：校正：ZielinskiW。等。离子液体用作氢化硅烷化反应中铑和铂催化剂的溶剂。分子2016211115
7. Correction: Zielinski, W., et al. Ionic Liquids as Solvents for Rhodium and Platinum Catalysts Used in Hydrosilylation Reaction. Molecules 2016, 21, 1115 [O] . Witold Zielinski, Rafal Kukawka, Hieronim Maciejewski, 2017

机译：更正：Zielinski，W.，et al。离子液体作为氢化硅烷化反应中铑和铂催化剂的溶剂。 molecules 2016,21,1115

Chapter 21 Tailoring Adsorption-Desorption Properties of Hydroamination Catalysts with Ionic Liquids

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