首页> 外文会议>ISOPE(International Society of Offshore and Polar Engineers) Ocean Mining Symposium Nov 8-10, 1999, Goa, India >Simultaneous Spectrophotometric Estimation of Iron, Copper, Cobalt and Nickel in Ocean Nodule Leach Liquor
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Simultaneous Spectrophotometric Estimation of Iron, Copper, Cobalt and Nickel in Ocean Nodule Leach Liquor

机译:分光光度法同时测定海洋结核浸出液中铁铜钴镍。

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During the development of a solvent extraction process for the separation of nickel and cobalt from ocean nodule sulphate leach liquor, there was a need for fast and accurate analytical method for determination of these elements in various process streams. For the determination of copper, nickel and cobalt which are present in gm/litre level, simultaneous visible spectrophotometric method developed in our laboratory was employed. Iron which is present at <0.2 g/1 was estimated by atomic absorption spectrophotometry. It has been found that Iron (III) seriously interferes with the determination of nickel giving almost 10% higher values as confirmed by classical gravimetric method. Therefore, an attempt has been made to develop a fast and accurate method for the simultaneous determination of copper, cobalt, nickel and iron by visible spectrophotometry. The method developed eliminates the need for separate estimation of iron by atomic absorption spectrophotometry and nickel by gravimetry.
机译:在开发用于从海藻硫酸盐浸出液中分离镍和钴的溶剂萃取方法的过程中,需要一种快速准确的分析方法来测定各种工艺物流中的这些元素。为了测定以克/升为单位的铜,镍和钴,采用了我们实验室开发的同时可见光分光光度法。通过原子吸收分光光度法估算<0.2 g / 1的铁含量。已经发现,铁(III)严重干扰了镍的测定,这通过经典的重量分析法得到了证实,其值几乎提高了10%。因此,已经尝试开发一种快速和准确的方法,用于通过可见分光光度法同时测定铜,钴,镍和铁。所开发的方法消除了通过原子吸收分光光度法对铁和通过重量法对镍的单独估算的需求。

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