首页> 外文会议>Italian Conference on Chemical and Process Engineering(ICheaP-6) vol.2; 20030608-11; Pisa(IT) >The effect of thermal ageing of PCL, PHB-V and their blends with starch in the biodegradation in soil compostage
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The effect of thermal ageing of PCL, PHB-V and their blends with starch in the biodegradation in soil compostage

机译:PCL,PHB-V及其与淀粉的共混物的热老化对土壤复合生物降解的影响

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摘要

Different proportions of starch were blended with poly(β-hydroxybutyrate)-co-poly(β-hydroxyvalerate) (PHB-V) or poly(ε-caprolactone) (PCL) by extrusion and the mechanical properties (maximum tensile strength, elongation at break and Young's modulus) and thermal properties (DSC) were determined. The biodegradability of the blends in soil compostage was also assessed after thermal ageing for 192,425 and 600 h at different temperatures. The maximum tensile strength of the blend PCL50 (containing 50% starch) was 35% lower than that of PCL, and that of PHB-V50 was 60% lower than for PHB-V, without thermal ageing. PHB-V blends were more biodegradable than PCL blends. For of the blends prepared, thermal ageing affected the biodegradation only of blend PHB-V25.
机译:将不同比例的淀粉与聚(β-羟基丁酸酯)-共聚(β-羟基戊酸酯)(PHB-V)或聚(ε-己内酯)(PCL)混合,并挤出,并观察其机械性能(最大拉伸强度,测定断裂和杨氏模量)和热性能(DSC)。在不同温度下热老化192,425和600 h后,还评估了混合物在土壤混合阶段的生物降解性。在没有热老化的情况下,共混物PCL50(含50%淀粉)的最大拉伸强度比PCL低35%,而PHB-V50的最大拉伸强度比PHB-V低60%。 PHB-V混合物比PCL混合物具有更高的生物降解性。对于所制备的共混物,热老化仅影响共混物PHB-V25的生物降解。

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