Two-Dimensional Polymers and Covalent Organic Frameworks

机译：二维聚合物和共价有机骨架

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Two-dimensional polymers and their layered frameworks (covalent organic frameworks: COFs) are a class of crystalline porous materials that allow an atomically precise integration of components into a 2D or 3D periodicity. 1 The recent synthetic progress has shown that 2D COFs are a versatile platform for designing functional materials with various applications. We have poineered the design and synthesis of π-electronic COFs by integrating various arenes and large π molecuels into the 2D polygon skeletons.2-19 In this talk, we focus on our challenge for the molecular design of COFs with periodically ordered and bicontinuously segregated p-n heterojunctions, which would provide a new molecular configuration and mechanism for optoelectronics and photovoltaics.

机译：二维聚合物及其分层框架（共价有机框架：COF）是一类晶体多孔材料，可将原子以原子方式精确地集成到2D或3D周期性中。 1最近的综合进展表明，二维COF是用于设计具有各种应用功能材料的多功能平台。通过将各种竞技场和较大的π分子整合到2D多边形骨架中，我们已经简化了π电子COF的设计和合成。2-19在本讲座中，我们将重点介绍对周期性有序和双连续分离的COF进行分子设计的挑战pn异质结，它将为光电子学和光伏技术提供新的分子构型和机理。

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《IUPAC 10th International conference on novel materials and their synthesis: Book of abstracts》|2014年|E33-E34|共2页
会议地点 Zhengzhou(CN)
作者
Donglin Jiang;
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Department of Materials Molecular Science, Institute for Molecular Science, National Institutes of Natural Sciences, 5-1 Higashiyama, Myodaiji, Okazaki 444-8787, Japan;

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Two-Dimensional Polymers and Covalent Organic Frameworks

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