首页> 外文会议>Macromolecular Symposia 209; Organometallic and Coordination Clusters and Polymers: Syntheses and Applications Symposium; 20040529-0601; London(CA) >Luminescence Properties of Organometallic/Coordination Oligomers and Polymers Containing Diphosphine and Diisocyanide Assembling Ligands: Comparison between Mononuclear Model Complexes and Polymers
【24h】

Luminescence Properties of Organometallic/Coordination Oligomers and Polymers Containing Diphosphine and Diisocyanide Assembling Ligands: Comparison between Mononuclear Model Complexes and Polymers

机译:有机金属/配位低聚物和含二膦和二异氰酸酯组装配体的聚合物的发光性质:单核模型配合物和聚合物之间的比较。

获取原文
获取原文并翻译 | 示例

摘要

This paper describes the luminescence properties of selected examples of homo- and mixed-bridging ligand-containing organometallic/coordination oligomers and polymers of copper(I), silver(I), palladium(I) and -(0.5), and platinum(0.5). The bridging ligands are the 1,8-diisocyano-p-menthane (dmb) and bis(diphenylphosphino)methane (dppm), -ethane (dppe), -propane (dppp), -butane (dppb), -pentane (dpppen), and -hexane (dpph), as well as bis(diphenyl-phosphino)acetylene (dpa) and bis(dimethylphosphino)methane (dmpm). The comparison between the mononuclear model complexes and the polymers of the emission maxima (λ_(max)) and emission lifetimes (τ_e) will be made, and interpreted by the presence of intrachain interactions and exciton phenomena.
机译:本文介绍了含均桥基和混合桥基配体的有机金属/配位低聚物以及铜(I),银(I),钯(I)和-(0.5)和铂(0.5)的聚合物的发光特性)。桥接配体是1,8-二异氰基-对-薄荷烷(dmb)和双(二苯基膦基)甲烷(dppm),-乙烷(dppe),-丙烷(dppp),-丁烷(dppb),-戊烷(dpppen) ,-己烷(dpph),双(二苯基膦基)乙炔(dpa)和双(二甲基膦基)甲烷(dmpm)。将进行单核模型配合物与发射最大值(λ_(max))和发射寿命(τ_e)的聚合物之间的比较,并通过链内相互作用和激子现象的存在来解释。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号