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Infrared-visible sum-frequency spectroscopic characterization of the molecular orientation of self-assembled monolayers of alkanethiols on obliquely deposited gold films

机译：倾斜沉积金膜上链烷硫醇自组装单分子层分子取向的红外可见和频光谱表征

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This paper reports on a detailed study that sought to establish an understanding of the molecular orientation of self-assembled monolayers (SAMs) formed from n-alkanethiols on obliquely deposited gold films. This study focuses on the azimuthal symmetry of the resonance signal obtained by rotation of the substrate about its normal. The important aspect of this work is to account for the anisotropic sum-frequency signal generated by gold and the preferred in- and out-of-plane orientations of the vibrational stretches.

机译：本文报道了一项详细的研究，旨在建立对由正烷硫醇在倾斜沉积的金膜上形成的自组装单分子层（SAMs）的分子取向的理解。这项研究的重点是通过绕基板法线旋转获得的共振信号的方位对称性。这项工作的重要方面是考虑由金产生的各向异性和频信号以及振动拉伸的首选面内和面外方向。

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《》|2003年|p.407-408|共2页
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Follonier; S.; Miller; W.J.; Abbott; N.L.; Knoesen; A.;
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中图分类无线电电子学、电信技术;
关键词
infrared spectra; visible spectra; optical harmonic generation; molecular orientation; monolayers; self-assembly; organic compounds; vibrational states; infrared-visible spectroscopy; sum-frequency spectroscopic characterization; molecular orientation; self-assembled monolayers; alkanethiols; obliquely deposited gold films; azimuthal symmetry; resonance signal; anisotropic sum-frequency signal; vibrational stretches; Au;

机译：红外光谱;可见光谱;光学谐波产生;分子取向;单层;自组装;有机化合物;振动状态;红外可见光谱;和频光谱表征;分子取向;自组装单层;烷硫醇;倾斜沉积的金膜方位对称共振信号各向异性和频信号振动拉伸Au;

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专利

1. Characterization of the molecular orientation of self-assembled monolayers of alkanethiols on obliquely deposited gold films by using infrared-visible sum-frequency spectroscopy [J] . Follonier S., Miller WJW., Abbott NL., Langmuir: The ACS Journal of Surfaces and Colloids . 2003,第25期

机译：红外可见和频光谱表征倾斜沉积金膜上链烷硫醇自组装单分子层的分子取向
2. Measurement of the Azimuthal Anchoring Energy of Liquid Crystals in Contact with Oligo(ethylene glycoI)-Terminated Self-Assembled Monolayers Supported on Obliquely Deposited Gold Films [J] . Brian H.Clare, Orlando Guzman, Juan J.de Pablo, Langmuir: The ACS Journal of Surfaces and Colloids . 2006,第10期

机译：与倾斜沉积的金膜上支撑的寡聚（乙二醇）端接的自组装单分子层接触的液晶的方位固定能的测量。
3. Molecular Orientation of Evaporated Pentacene Films on Gold:Alignment Effect of Self-Assembled Monolayer [J] . W.S.Hu, Y.T.Tao, Y.J.Hsu, Langmuir: The ACS Journal of Surfaces and Colloids . 2005,第6期

机译：蒸发的并五苯薄膜在金上的分子取向：自组装单分子膜的取向效应
4. Infrared-Visible Sum-Frequency Spectroscopic Characterization of the Molecular Orientation of Self-Assembled Monolayers of Alkanethiols on Obliquely Deposited Gold Films [C] . S. Follonier, W. J. Miller, N. L. Abbott, Annual Meeting of the IEEE Lasers and Electro-Optics Society . 2003

机译：倾斜沉积金薄膜在斜沉积的金硫醇中自组装单层的分子取向的红外可见的和频谱表征
5. Scanning tunneling microscopy studies of growth medium & temperature dependent structural phases of alkanethiol self-assembled monolayers, reactive self-assembled monolayers, & flat gold nanoparticle/indium tin oxide substrates and a scanning surface photovoltage microscopy study for local mechanical stress characterization in complementary metal oxide semiconductor devices. [D] . Dahanayaka, Dahanayaka Liyanage Daminda Hemal. 2010

机译：烷烃硫醇自组装单分子层，反应性自组装单分子层，扁平金纳米颗粒/铟锡氧化物基质的生长介质和温度依赖性结构相的扫描隧道显微镜研究，以及互补金属氧化物中局部机械应力表征的扫描表面光电压显微镜研究半导体器件。
6. Microwave-Accelerated Surface Modification of Plasmonic Gold Thin Films with Self-Assembled Monolayers of Alkanethiols [O] . Tsehai A.J. Grell, Anginelle M. Alabanza, Karen Gaskell, -1

机译：带有自组装烷烃硫醇单分子膜的等离子金薄膜的微波加速表面改性
7. Measurement of the Azimuthal Anchoring Energy of Liquid Crystals in Contact with Oligo(ethylene glycol)-Terminated Self-Assembled Monolayers Supported on Obliquely Deposited Gold Films [O] . -1

机译：测量与寡核苷酸（乙二醇）接触的液晶的方位角锚固能量（乙二醇） - 替代的自组装单层支撑在斜沉积的金膜上
8. Self-Assembled Monolayers of Alkanethiols on Gold: Monolayers Derived From Two Components with Alkane Chains of Different Lengths. [R] . Folkers, J. P., Laibinis, P. E., Whitesides, G. M. 1992

机译：在金上自组装的alkanethiols单层膜：由两种不同长度的烷烃链组成的单层膜。

Infrared-visible sum-frequency spectroscopic characterization of the molecular orientation of self-assembled monolayers of alkanethiols on obliquely deposited gold films

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