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Doping of thin plasma polymerized aniline films

机译:等离子体聚合苯胺薄膜的掺杂

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Summary form only given. Polymers can be used as conductors ofelectricity and as “smart” materials, which change one ormore properties when activated by an electrical signal. Applicationsinclude control of electrostatic charge, batteries, fuel cells, drugdelivery devices, optical switching, optical displays, capacitors,microactuators, field-effect transistors and light emitting diodes. Theelectroactive properties of plasma polymerized aniline films have beenstudied recently by others. In our work, we have fabricated plasmapolymerized aniline resistors. To measure the resistivity of the film,gold electrodes were sputtered onto ceramic substrates. For comparisonpurposes, one electrode structure remained “blank” withoutfurther processing. Plasma polymerized aniline film with thickness 0.2μm was deposited over the remaining electrode structures. Theseresistors were annealed in a nitrogen environment at 125 C for 4 hours.While the plasma polymerized aniline film on one resistor remainedundoped the film on another was doped by immersion in a 1 molar HClsolution for 7 hours. Doping was followed by vacuum drying. Resistorvalues for the blank electrode structure, tor the resistor with undopedfilm and for the resistor with doped film were measured from the slopeof volt-ampere characteristics recorded with a Keithley 617Electrometer. The undoped film had a conductivity less than 4×10-2 s/cm while the film doped with the liquid HCl treatmenthad a conductivity of 4×10-10 to s/cm, a result that isconsistent with earlier work by Gong et al. (1998)
机译:仅提供摘要表格。聚合物可用作导体 电力和“智能”材料,它们会改变一种或 由电信号激活时具有更多特性。应用领域 包括控制静电,电池,燃料电池,药物 传送设备,光学开关,光学显示器,电容器, 微致动器,场效应晶体管和发光二极管。这 等离子体聚合苯胺薄膜的电活性已经得到了证实。 最近被其他人研究。在我们的工作中,我们制造了等离子 聚合苯胺电阻器。为了测量薄膜的电阻率, 将金电极溅射到陶瓷基板上。为了比较 目的,一个电极结构保持“空白”,没有 进一步处理。等离子聚合苯胺薄膜,厚度为0.2 在其余的电极结构上沉积了μm。这些 将电阻器在氮气环境中于125 C退火4小时。 在一个电阻上保留了等离子体聚合的苯胺膜 将未掺杂的薄膜通过浸入1摩尔的HCl中进行掺杂 溶液7小时。掺杂之后进行真空干燥。电阻器 空白电极结构的值,将电阻器与未掺杂的 薄膜和用于掺杂薄膜的电阻器是从斜率测量的 吉时利617记录的伏安特性 静电计。未掺杂的膜的电导率小于4×10 -2 s / cm,而薄膜用液态HCl处理掺杂 的电导率为s / cm的4×10 -10 与龚等人的早期工作一致。 (1998)

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