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THE CATALYTIC ACTIVITY OF TERNARY CATALYSTS FOR METHANOL OXIDATION

机译:甲醇氧化三元催化剂的催化活性

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The Pure Pt, PtRu and PtRuM (M=Ni, Mo, Sn, W) electrocatalysts were synthesized using a NaBH_4 reduction method. The alloy characterization of the electrocatalysts were determined by X-ray diffraction (XRD) and Transmission Electron Microscopy (TEM). The electrochemical properties of the electrocatalysts were analyzed via methanol electro-oxidation and Cyclic Voltammetry. Methanol oxidation of the PtRuNi and PtRuW electrocatalyst was much higher than that of PtRu electrocatalyst. The other catalysts electrocatalysts showed low Methanol oxidations, but higher specific activities than that of the PtRu electrocatalyst. Therefore, the addition of a third metal to binary PtRu electrocatalyst imparted good catalytic activity to the anode surface.
机译:使用NABH_4还原方法合成纯PT,PTRU和撞击(M = NI,MO,SN,W)电催化剂。通过X射线衍射(XRD)和透射电子显微镜(TEM)测定电催化剂的合金表征。通过甲醇电氧化和环伏酯分析电催化剂的电化学性质。 PTRUNI和PTRUW电催化剂的甲醇氧化远高于PTRU电催化剂。其它催化剂电催化剂显示出低甲醇氧化,但比PTRU电催化剂更高的比活性。因此,将第三金属加入二元斑块电催化剂赋予阳极表面的良好催化活性。

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