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Unusual framework stabilization of Cu(II) and Cu(I) ions in a novel copper-substituted aluminophosphate with AEN topology prepared by one pot synthesis

机译：一锅合成制备的具有AEN拓扑结构的新型铜取代铝磷酸盐中的Cu（II）和Cu（I）离子异常骨架稳定

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A novel copper-substituted aluminophosphate (CuIST-2) has been synthesized using methylamine as a templating agent. X-Ray diffraction studies provide evidence for an AEN topology similar to the parent Cu-free IST-2. An increase of the cell parameters suggested an isomorphous substitution of framework aluminium by copper. Combined cyclic voltammetry, H2-TPR, FTIR and cw EPR provide independent proof for an unusual framework position of Cu(II) ions in the as-synthesized phase and the further stabilization of both framework Cu(II) and Cu(I) in the air-calcined material.

机译：使用甲胺作为模板剂合成了一种新型的铜取代铝磷酸盐（CuIST-2）。 X射线衍射研究为类似于母体无铜IST-2的AEN拓扑提供了证据。电池参数的增加表明框架铝被铜同构取代。联合循环伏安法，H2-TPR，FTIR和cw EPR为合成态相中Cu（II）离子的异常骨架位置提供了独立的证据，并进一步证明了Cu（II）和Cu（I）骨架在框架中的进一步稳定。空气煅烧材料。

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《International Zeolite Conference》|2007年|1-8|共8页
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SUI Xiaoqing; WANG Kun; ZHENG Shuhua; LIN Li;
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2. Structural investigation of metal-organic cu(ii) coordination frameworks constructed from n-donor and α, ω-dicarboxylate ligands by one pot synthesis: Zigzag strands, layered networks and its interaction with lattice water molecules [J] . Kathalikkattil A.C., Subramanian P.S., Eringathodi S. Journal of chemical crystallography . 2010,第12期

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机译：一锅合成由N-给体和α，ω-二羧酸配体构成的金属有机Cu（II）配位结构的结构研究：之字形链，层状网络及其与晶格水分子的相互作用
4. Unusual framework stabilization of Cu(II) and Cu(I) ions in a novel copper-substituted aluminophosphate with AEN topology prepared by one pot synthesis [C] . Z. Gabelica, A. Fernandes, M. F. Ribeiro, International Zeolite Conference . 2007

机译：在新型铜取代的铝磷酸磷酸铝中的Cu（II）和Cu（I）离子的异常骨架稳定性，通过一个罐合成制备的Zeen拓扑
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7. Structural State and Redox Behavior of Framework Co(II) in CoIST-2: A Novel Cobalt-Substituted Aluminophosphate with AEN Topology [O] . -1

机译：Coist-2框架CO（II）的结构状态和氧化还原行为：具有AEN拓扑的新型钴取代铝磷酸铝

Unusual framework stabilization of Cu(II) and Cu(I) ions in a novel copper-substituted aluminophosphate with AEN topology prepared by one pot synthesis

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