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首页> 外文会议>Silicones and silicone-modified materials symposium >Chapter 4 Fluorinated Copoly(carbosiloxane)s: Synthesis, Copolymerization, and Cross-Linked Networks
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Chapter 4 Fluorinated Copoly(carbosiloxane)s: Synthesis, Copolymerization, and Cross-Linked Networks

机译：第4章氟化共聚（碳硅氧烷）：合成，共聚和交联网络

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摘要

A desirable combination of properties of siloxane and fluorinated polymers may be achieved by preparation of fluorinated copoly(carbosiloxane)s. A series of novel non-fluorinated (Ⅰ) and fluorinated α,ω-bis(glycidyloxypropyl)-pentasiloxanes (Ⅱ-Ⅲ) were prepared and subsequently copolymerized with piperazine to form well-defined non-fluorinated (IV) and fluorinated copoly(carbosiloxane)s (Ⅴ-Ⅵ) with high molecular weights. Ⅰ-Ⅲ were also reacted with α,ω-diaminoalkanes (a-c) to form cross-linked networks or films (Ⅶa-c, Ⅷa-c, and Ⅸa-c). Mechanical, surface, and thermal properties of these were studied. Anti-foul and foul-release properties of the films were evaluated by settlement and removal tests with spores of the green alga, Ulva. These films represent a novel class of epoxies with an unusual combination of properties: high flexibility, low T_g, hydrophobic surfaces, and good thermal stability.
机译：硅氧烷和氟化聚合物的性能的理想组合可以通过制备氟化共聚（碳硅氧烷）来实现。制备了一系列新型的非氟化（Ⅰ）和氟化的α，ω-双（环氧丙氧基丙基）-五硅氧烷（Ⅱ-Ⅲ），然后与哌嗪共聚形成定义明确的非氟化（IV）和氟化的共聚（硅氧烷）高分子量的）（Ⅴ-Ⅵ）。 Ⅰ-Ⅲ还与α，ω-二氨基链烷（a-c）反应形成交联的网络或薄膜（Ⅶa-c，Ⅷa-c和Ⅸa-c）。研究了这些材料的机械，表面和热性能。通过用绿藻类Ulva的孢子的沉降和去除测试，评价了膜的防污和防污性能。这些薄膜代表了新型环氧树脂，具有非凡的性能组合：高柔韧性，低T_g，疏水表面和良好的热稳定性。

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