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Chapter 9 Application of Poly(styrene-b-methylphenylsiloxane) Diblock Copolymers for the Steric Stabilization of Organic Polymerizations in Carbon Dioxide

机译：第9章聚（苯乙烯-b-甲基苯基硅氧烷）二嵌段共聚物在二氧化碳中有机聚合立体稳定化中的应用

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The ability to isolate the individual stereochemical isomers of the cyclic methylphenylsiloxanes provides one with novel siloxane monomers for the preparation of block copolymers. For the case of the kinetically controlled anionic ring-opening polymerization of the cyclic trimers, one is able to synthesize poly(styrene-b-methylphenylsiloxane) (PS-b-PMPS) diblock copolymers of well defined composition and structure. Herein we describe an investigation of the application of PS-b-PMPS as a surfactant for the dispersion polymerization of styrene in supercritical carbon dioxide.

机译：分离环状甲基苯基硅氧烷的各个立体化学异构体的能力为制备嵌段共聚物提供了一种具有新型硅氧烷单体的化合物。对于环状三聚体的动力学控制的阴离子开环聚合的情况，人们能够合成具有明确定义的组成和结构的聚（苯乙烯-b-甲基苯基硅氧烷）（PS-b-PMPS）二嵌段共聚物。在本文中，我们描述了PS-b-PMPS作为表面活性剂在苯乙烯在超临界二氧化碳中分散聚合的表面活性剂的研究。

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《Silicones and silicone-modified materials symposium》|2007年|116-133|共18页
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Abhijit V. Jadhav; Siddharth V. Patwardhan; Hyeon Woo Ahn; Craig E. Selby; James O. Stuart; Xiao Kang Zhang; Chung Mien Kuo; Ephraim A. Sheerin; Richard A. Vaia; Steven D. Smith; Stephen J. Clarson;
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Chapter 9 Application of Poly(styrene-b-methylphenylsiloxane) Diblock Copolymers for the Steric Stabilization of Organic Polymerizations in Carbon Dioxide

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