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Chapter 18 Hydrophobic Silsesquioxane Nanoparticles and Nanocomposite Surfaces: An Overview of the Synthesis and Properties of Fluorinated Polyhedral Oligomeric SilSequioxanes (POSS) and Fluorinated POSS Nanocomposites

机译：第十八章疏水倍半硅氧烷纳米颗粒和纳米复合材料表面：氟化多面体低聚倍半硅氧烷（POSS）和氟化POSS纳米复合材料的合成和性能概述

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Fluorinated Polyhedral Oligomeric Silsesquioxanes are hydrophobic nanoparticles. One compound, FD_8T_8, is ultrahydrophobic, possessing a water contact angle of 154°. This is believed to be the most hydrophobic and lowest surface tension crystalline substance known. Analysis of the x-ray crystal structure indicates a large number of Si...F contacts may lead to ultrahydrophobicity. Hydrophobicity of poly(chlorotrifluoroethylene) nanocomposites also increases with the incorporation of FluoroPOSS and will be discussed.

机译：氟化多面体低聚倍半硅氧烷是疏水性纳米颗粒。一种化合物FD_8T_8是超疏水的，具有154°的水接触角。据信这是已知的最疏水和最低表面张力的结晶物质。 X射线晶体结构分析表明，大量的Si ... F接触可能会导致超疏水性。聚（氯三氟乙烯）纳米复合材料的疏水性也会随着FluoroPOSS的加入而增加，将对此进行讨论。

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《Silicones and silicone-modified materials symposium》|2007年|290-300|共11页
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Joseph M. Mabry; Ashwani Vij; Brent D. Viers; Wade W. Grabow; Darrell Marchant; Scott T. Iacono; Patrick N. Ruth; Isha Vij;
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机译：半结晶多面体低聚倍半硅氧烷（pOss）纳米复合材料的力学和表面性质测定

Chapter 18 Hydrophobic Silsesquioxane Nanoparticles and Nanocomposite Surfaces: An Overview of the Synthesis and Properties of Fluorinated Polyhedral Oligomeric SilSequioxanes (POSS) and Fluorinated POSS Nanocomposites

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