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Performance of the Savannah River Site Coulometer for Neptunium Process Accountability and Neptunium Oxide Product Characterization

机译:萨凡纳河站点库仑法对N工艺问责制和氧化ept产物表征的性能

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The Savannah River Site’s (SRS) H-Area B-Line (HB-Line) nuclear facility is processing neptunium solutions for stabilization as an oxide. The oxide will eventually be reprocessed and fabricated into target material and the ~237Np irradiated to produce ~238Pu in support of National Aeronautics and Space Administration space program missions. As part of nuclear materials accountability, solution concentrations were measured using a high-precision controlled-potential coulometer developed and manufactured at the SRS for plutonium accountability measurements~ 1. The Savannah River Site Coulometer system and measurement methodology for plutonium meets performance standards in ISO 12183-2005, “Controlled-Potential Coulometric Assay of Plutonium.”~ 2,3,4,5 The Department of Energy (DOE) does not produce or supply a neptunium metal certified reference material, which makes qualifying a measurement method and determining accuracy and precision difficult. Testing and performance of the Savannah River Site Coulometer indicates that it can be used to measure neptunium process solutions and dissolved neptunium oxide without purification for material control and accountability purposes. Savannah River Site’s Material Control and Accountability organization has accepted the method uncertainty for accountability and product characterization measurements.
机译:萨凡纳河站点(SRS)的H区B线(HB-Line)核设施正在处理processing溶液,以使其稳定化为氧化物。该氧化物最终将被重新加工并制成目标材料,并辐射〜237Np以产生〜238Pu,以支持美国国家航空和航天局的太空计划任务。作为核材料问责制的一部分,使用由SRS开发和制造的用于account问责性测量的高精度可控电库仑计测量溶液浓度〜1. Savannah River Site Coulometer系统和p的测量方法符合ISO 12183的性能标准-2005年,“ Control的可控库仑分析法”。〜2,3,4,5能源部(DOE)不生产或不提供经metal金属认证的参比材料,这使测量方法合格并确定准确性和精度难。 Savannah River Site Coulometer的测试和性能表明,无需进行纯化即可用于测量process工艺溶液和溶解的氧化un,以进行材料控制和问责制。萨凡纳河工地的材料控制和责任组织已接受方法不确定性的责任和产品特性测量。

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