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High-power charge/discharge properties of LiFePO_4/carbon composites with various carbon materials

机译:具有各种碳材料的LiFepo_4 /碳复合材料的高功率充电/放电性能

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Electrochemical properties of LiFePO_4/carbon composites with various carbon materials were investigated to achieve high-rate charge and discharge properties. LiFePCVcarbon composites were synthesized by a pyrolysis of a LiFePO_4 precursor solution added with porous graphite or particulate carbon powders. The LiFePO_4/porous-graphite composite had a microstructure in which LiFePO_4 particles existed on carbon surface and within pores. The LiFePO_4/particulate-carbon composite had a microstructure in which each carbon particle was covered with LiFePO_4 fine particles. The LiFePO_4/porous-graphite and the LiFePO_4/particulate-carbon composite electrodes showed high discharge capacities of 69 and 30 mAh g~(-1) at a high current density of 4000 mA g~(-1). The high electronic conductivity in the LiFePCVporous-graphite composite contributed to achieving the large discharge capacity at the high current density.
机译:研究了LiFepo_4 /碳复合材料的电化学性能,具有各种碳材料,以实现高速率充电和放电性能。通过加入多孔石墨或颗粒碳粉末的LiFePO_4前体溶液的热解合成Lifepcvcarbon复合材料。 LiFePO_4 /多孔石墨复合材料具有微结构,其中LifePo_4颗粒存在于碳表面和孔内。 LiFePO_4 /颗粒碳复合物具有微结构,其中每种碳颗粒覆盖有LiFePO_4细颗粒。 LiFePO_4 /多孔石墨和LiFePO_4 /颗粒 - 碳复合电极显示出高电流密度为4000mA G〜(-1)的高放电容量。 Lifepcvorous-石墨复合材料中的高电子电导率有助于实现高电流密度的大放电容量。

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