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Study on Degradation of Crystal Violet by UV/Fenton/Heteropolyacid System

机译:UV / Fenton /杂多酸体系降解结晶紫的研究

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The degradation of an azo dye crystal violet by UV/Fenton oxidation process in the presence of heteropolyacid solution has been investigated. The degradation rate is strongly dependent on the pH, initial concentrations of the dye, Fe2+, H2O2 and phosphotungstic acid. The effect of these parameters has been studied and the optimal reacting conditions were experimentally determined. It was found to be initial pH 2.7, [H2O2] =71 mM, [Fe2+] = 0.5 mM, [dye]0 = 20 mg/L, phosphotungstic acid concentration is 24 mg/L. Under optimal conditions, 95% degradation efficiency of dye in the presence of heteropolyacid solution was achieved after 60 min of reaction. The experimental results showed that the UV/Fenton oxidation process was an effective process for the degradation of crystal violet at low H2O2 and Fe2+ concentrations. Meanwhile, this research also proved that heteropolyacid could improve the photocatalytic efficiency in the UV/Fenton reaction as an efficient activator.
机译:已经研究了在杂多酸溶液存在下通过UV / Fenton氧化过程降解偶氮染料结晶紫的方法。降解速率很大程度上取决于pH值,染料的初始浓度,Fe 2 + ,H 2 O 2 和磷钨酸。研究了这些参数的影响,并通过实验确定了最佳反应条件。发现其初始pH值为2.7,[H 2 O 2 ] = 71 mM,[Fe 2 + ] = 0.5 mM,[染料] 0 = 20 mg / L,磷钨酸浓度为24 mg / L。在最佳条件下,反应60分钟后,在杂多酸溶液存在下,染料的降解效率达到95%。实验结果表明,UV / Fenton氧化工艺是低H 2 O 2 和Fe 2 + 时结晶紫降解的有效方法。 sup>浓度。同时,这项研究还证明了杂多酸可以作为一种有效的活化剂提高UV / Fenton反应中的光催化效率。

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