Vibrational and Rotational Excitation and Dissociation of CO_2 Reexamined

机译：振动和旋转激发和离解的CO_2

获取原文

页面导航

摘要
著录项
相似文献
相关主题

摘要

Quantum chemistry calculations are undertaken to elucidate the potential energy surfaces of the lowest singlet (S0) and triplet (T1) electronic states of CO_2. The region of the potential energy surfaces where the SO and Tl states cross is determined and its effect on the CO_2 dissociation rate coefficients is discussed. It is suggested that the singlet-triplet transition is the bottleneck in the CO_2 excitation process that controls the temperature dependence of the dissociation rate.

机译：进行量子化学计算以阐明CO_2的最低单重态（S0）和三重态（T1）电子态的势能面。确定了势能表面的SO和T1态交叉的区域，并讨论了其对CO_2离解速率系数的影响。提示单重态-三重态转变是CO_2激发过程中的瓶颈，它控制着解离速率的温度依赖性。

著录项

来源
《AIAA aerospace sciences meeting including the new horizons forum and aerospace exposition》|2011年|p.5960-5973|共14页
会议地点
作者
Richard Jaffe;
展开▼
作者单位

展开▼
会议组织
原文格式 PDF
正文语种
中图分类航空;
关键词

相似文献

外文文献
中文文献
专利

1. Translational and rotational excitation of the CO_2(00~00)vibrationless state in the collisional quenching of higly vibrationally excited 2-methylpyrazine:Kinetics and dynamics of large energy transfers [J] . Eric T.Sevy, Seth M.Rubin, Zhen Lin, The Journal of Chemical Physics . 2000,第12期

机译：高振动激发的2-甲基吡嗪碰撞猝灭中CO_2（00〜00）无振动态的平移和旋转激发：大能量传递的动力学和动力学
2. Theoretical resonant electron-impact vibrational excitation, dissociative recombination and dissociative excitation cross sections of ro-vibrationally excited BeH+ ion [J] . Laporta V., Chakrabarti K., Celiberto R., Plasma physics and controlled fusion . 2017,第4期

机译：理论共振电子 - 冲击振动激发，离灭重组和RO-振动激发的分离激励截面截面+离子
3. Theoretical resonant electron-impact vibrational excitation, dissociative recombination and dissociative excitation cross sections of ro-vibrationally excited BeH+ ion [J] . Laporta V., Chakrabarti K., Celiberto R., Plasma physics and controlled fusion . 2017,第4期

机译：理论共振电子 - 冲击振动激发，离灭重组和RO-振动激发的分离激励截面截面+离子
4. Vibrational and Rotational Excitation and Dissociation of CO_2 Reexamined [C] . Richard Jaffe AIAA aerospace sciences meeting including the new horizons forum and aerospace exposition . 2011

机译：振动和旋转激发和CO_2的解离释放
5. Protein and lantibiotic sequencing by gas phase dissociation involving vibrational excitation and ion electron reactions. [D] . Kalli, Anastasia. 2009

机译：通过气相解离进行蛋白质和羊毛硫抗生素测序，涉及振动激发和离子电子反应。
6. Effects of vibrational excitation on the F + H2O → HF + OH reaction: dissociative photodetachment of overtone-excited F–H–OH– [O] . Amelia W. Ray, Jianyi Ma, Rico Otto, 2017

机译：振动激发对F + H2O→HF + OH反应的影响：泛音激发的F–H–OH –的解离光解
7. Electron-impact resonant vibrational excitation and dissociation processes involving vibrationally excited N2 molecules [O] . Laporta, V., Little, D. A., Celiberto, R., 2014

机译：电子碰撞共振振动激发和解离涉及振动激发的N2分子的过程
8. Compilation of Low Energy Electron Collision Cross Section Data. Part I. Ionization, Dissociative Processes, and Vibrational and Rotational Excitation [R] . Keiffer, L. J. 1969

机译：低能电子碰撞截面数据的编制。第一部分电离，解离过程，振动和旋转激发

Vibrational and Rotational Excitation and Dissociation of CO_2 Reexamined

摘要

著录项

相似文献

相关主题

期刊订阅