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High Rate Reactive Aluminium-Doped Zinc Oxide (AZO) Deposition by Dual Rotatable Magnetron Sputtering

机译:双旋转磁控溅射高速率反应性掺杂铝的氧化锌(AZO)沉积

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There is a strong market demand for high rate deposition of thin film oxides onto flexible and rigid substrates. The primary sectors for such materials span established and new growing markets: 1. Capacitive touch panel film& glass-reactive SiO_2 layers and indium tin oxide (ITO) 2. Transparent conducting oxides (TCO) layers for flexible solar cells - aluminum doped zinc oxide (AZO) & ITO 3. High gas barrier film for PV and OLED applications -aluminum oxide (Al_2O_3) 4. Anti-reflective layer stacks on visual displays - SiO_2/ Nb_2O_5 5. Solar control architectural glazing - Si_3N_4, AlN, ZnO, ZnSnO (ZTO), AZO These layers are predominately deposited by magnetron sputtering. In the case of SiO_2 and Al_2O_3, the process is a reaction between the metallic target material and oxygen gas. Although reactive sputtering is now the dominant industrial method for thin film oxides, currently, for TCO layers used in the solar cell industry the deposition is non-reactive from a ceramic target material with a composition similar to the chemistry of the final layer. This presentation focuses on reactive deposition methods for TCO layers and the means to increase rates via process feedback control and hence reduce layer costs. In addition, the advantages of rotatable magnetrons as opposed to planar magnetrons will be presented. This will focus on the inherent benefits but also means to reduce defects and control the plasma at the growing film by the means of better magnetic confinement of electrons via magnetic coupling of two cathodes.
机译:市场上强烈要求将薄膜氧化物高速沉积在柔性和刚性基板上。此类材料的主要领域涵盖已建立的市场和新兴市场:1.电容式触摸屏薄膜和玻璃反应性SiO_2层和氧化铟锡(ITO)2.柔性太阳能电池的透明导电氧化物(TCO)层-铝掺杂氧化锌( AZO)和ITO 3.用于PV和OLED应用的高阻气膜-氧化铝(Al_2O_3)4.视觉显示器上的抗反射层堆叠-SiO_2 / Nb_2O_5 5.日光控制建筑玻璃-Si_3N_4,AlN,ZnO,ZnSnO(这些层主要是通过磁控溅射沉积的。在SiO_2和Al_2O_3的情况下,该过程是金属靶材料与氧气之间的反应。尽管现在反应溅射是用于薄膜氧化物的主要工业方法,但是目前,对于太阳能电池工业中使用的TCO层,沉积是由具有与最终层化学组成相似的陶瓷靶材料进行的非反应性沉积。本演讲重点介绍了用于TCO层的反应性沉积方法,以及通过工艺反馈控制来提高速率从而降低层成本的方法。另外,将展示与平面磁控管相反的可旋转磁控管的优点。这将侧重于固有优点,而且还意味着通过两个阴极的磁耦合更好地限制电子,从而减少缺陷并控制生长膜处的等离子体。

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