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Nanoparticles/Intermediate Reflective Layer Approach for Light Trapping in Silicon Tandem Solar Cells

机译:纳米粒子/中间反射层方法用于硅串联太阳能电池中的光捕获

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The concept of amorphous (a-Si:H)/microcrystalline (μc-Si:H) silicon tandem solar cells offers the potential for high-efficiency and low fabrication costs. Because of the small diffusion length of the generated electron-hole pairs in a-Si:H, the absorber thickness is limited to a few hundred nms. Therefore, photons at longer wavelengths are only poorly absorbed in the a-Si:H layer. Concepts for photon management are required to increase the absorption in the a-Si:H cell: the incorporation of an intermediate reflective layer (IRL) between the a-Si:H and μc-Si:H cells in combination with texturing can provide efficient light manipulation. The scattering occurs when the wavelength corresponds to the feature size of the texture, and a difficulty arises from the wide spectral range of absorption of the tandem cells (350-1100 nm). Our approach is to make use of the localized electro-magnetic field amplification that occurs in the vicinity of a metal surface through the eτ_citation of localized surface plasmons, which are resonantly coupled to metallic nanoparticles (NPs). Here the light scattering is investigated from arrays of copper NPs in order to determine design principles forplasmon-enhanced particle light trapping. To enhance forward scattering towards the μc-Si:H cell we introduce Cu NPs on the IRL dielectric ZnO layers.
机译:非晶(a-Si:H)/微晶(μc-Si:H)硅串联太阳能电池的概念为高效率和低制造成本提供了潜力。由于在a-Si:H中产生的电子-空穴对的扩散长度小,吸收体的厚度被限制在几百纳米。因此,较长波长的光子仅在a-Si:H层中吸收不良。需要进行光子管理的概念以增加a-Si:H电池的吸收:在a-Si:H和μc-Si:H电池之间引入中间反射层(IRL)并结合纹理化可以提供有效的灯光操纵。当波长对应于纹理的特征尺寸时发生散射,并且由于串联细胞的宽吸收光谱范围(350-1100nm)而引起困难。我们的方法是利用通过激发与金属纳米粒子(NPs)耦合的局部表面等离子体激元在金属表面附近发生的局部电磁场放大。在这里,从铜纳米粒子的阵列中研究光散射,以确定用于等离激元增强的粒子光捕获的设计原理。为了增强向μc-Si:H电池的向前散射,我们在IRL介电质ZnO层上引入Cu NP。

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