Preparation of diclofop-methyl enantiomers by a semi-preparative high-performance liquid chromatography

机译：半制备型高效液相色谱法制备双氯氟甲基对映体

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A chiral stationary phase (CSP) was prepared by coating cellulose tris(4-methylbenzoate) (CTMB) onto aminopropylated silica gel. Chiral herbicide diclofop-methyl (DM) was well resolved on analytical coated-CTMB CSP using 85/15 n-hexane/isopropanol as the mobile phase by high-performance liquid chromatography (HPLC), and the semi-preparation of DM enantiomers was conducted by the semi-chromatography. With a concentration 10000 ppm and a 20 µL loop, the yields of (+)-DM and (−)-DM were 1.590 mg/h and 1.583 mg/h, respectively.

机译：通过将纤维素三（4-甲基苯甲酸酯）（CTMB）涂覆到氨基丙基化硅胶上来制备手性固定相（CSP）。通过高效液相色谱（HPLC）在85/15正己烷/异丙醇作为流动相的分析型包被CTMB CSP上很好地拆分了手性除草剂二氯双氟甲基（DM），并进行了DM对映异构体的半制备通过半色谱法。在浓度为10000 ppm和定量回路为20 µL的情况下，（+）-DM和（-）-DM的产量分别为1.590 mg / h和1.583 mg / h。

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《2011 Second International Conference on Mechanic Automation and Control Engineering》|2011年|p.3305-3307|共3页
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Lixia Jin; Weiliang Gao; Chunmian Lin; Datong Zhang;
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中图分类计算技术、计算机技术;
关键词
Cellulose tris(4-methylbenzoate); chiral separation; diclofop-methyl; semi-preparation;

机译：纤维素三（4-甲基苯甲酸酯）;手性分离;二氟甲基;半制备;

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Preparation of diclofop-methyl enantiomers by a semi-preparative high-performance liquid chromatography

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