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The Green Recycling Process of Flame-Retarded High Impact Polystyrene Resin

机译:阻燃高抗冲聚苯乙烯树脂的绿色回收工艺

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In order to reduce the bad effect of the impurities on the mechanical performance and eliminate the pollution of toxic substances on the recycled product of flame-retarded high impact polystyrene(HIPS) resin, a new process of recycling HIPS resin from waste household appliance housing was developed in this paper, the nature d-limonene and low toxic npropanol were respectively selected as the solvent and precipitant of HIPS resin, the influences of HIPS concentration, precipitating temperature, stirring speed on the characteristic of HIPS precipitation particle were investigated. The experimental results showed that the particles size and shape of HIPS precipitation can meet the recycling process requirement when the HIPS concentration was about 15wt%, the volume ratio of n-propanol to HIPS solution was controlled to 3:1, and the precipitating operation was carried out under over 2000r/min of stirring speed and at 30°C. It was also found that near 90wt% of polybrominated diphenyl ethers existing in the flame-retarded HIPS resin was removed by this recycling process, and the recovery rate of polystyrene reached 97 wt %, so clean and high purity recycled HIPS resin was obtained.
机译:为了减少杂质对机械性能的不利影响并消除有毒的物质对阻燃高抗冲聚苯乙烯(HIPS)树脂回收产品的污染,一种从废旧家用电器外壳中回收HIPS树脂的新方法是本文开发了天然d-柠檬烯和低毒丙醇作为HIPS树脂的溶剂和沉淀剂,研究了HIPS浓度,沉淀温度,搅拌速度对HIPS沉淀颗粒性能的影响。实验结果表明,当HIPS浓度约为15wt%,正丙醇与HIPS溶液的体积比控制为3:1,且沉淀操作为HPS时,HIPS沉淀物的粒径和形状可以满足回收工艺要求。在超过2000r / min的搅拌速度和30°C下进行。还发现通过该再循环过程除去了阻燃的HIPS树脂中存在的近90wt%的多溴二苯醚,并且聚苯乙烯的回收率达到97wt%,因此获得了清洁和高纯度的再循环HIPS树脂。

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