Synthesis of molecular dodecanuclear carbon-centered rhenium cluster Re12CS17 and its conducting properties

机译：分子十二碳核为中心的cluster簇Re 12 CS 17 的合成及其导电性能

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The unique dodecanuclear cluster compound Re12CS17 was prepared and studied by X-ray, complex impedance method and density functional theory (DFT). The compound possesses semiconducting properties. Computer simulations showed that the Re and S atoms at the external borders of the neighboring molecules Re12CS17 can form strong intermolecular bonds Re … S, similar to the intermolecular bonds of Mo … S cuboctahedron Mo6S8 molecules in the Chevrel phases.

机译：通过X射线，复阻抗方法和密度泛函理论（DFT），制备并研究了独特的十二烷核簇化合物Re 12 CS 17 。该化合物具有半导体性能。计算机模拟表明，在邻近分子Re 12 CS 17 的外边界上的Re和S原子可以形成强分子间键Re…S，类似于Mo…S立方八面体Mo 6 S 8 分子处于Chevrel相。

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《34th International Convention on Information and Communication Technology, Electronics and Microelectronics》|2011年|p.19-20|共2页
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Fedorov V. E.; Gabuda S. P.; Kozlova S. G.; Gayfulin I. M.; Mironov Y. V.; Rizhikov M. R.; Uvarov N. F.;
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中图分类信息处理（信息加工）;通信;
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Synthesis of molecular dodecanuclear carbon-centered rhenium cluster Re12CS17 and its conducting properties

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