【24h】

DYNAMIC PROPERTIES OF CROSSLINKED POLYOLEFIN FOAMS

机译:交联聚烯烃泡沫的动态特性

获取原文

摘要

The material of choice in the foam industry for many years was Ethylene-Vinyl Acetate copolymers (EVA). This dominance was based on its flexibility, adhesion performance, and foaming window. In the last ten years, ethylene-a-olefin inter-polymers (or Polyolefin Elastomers (POE)) have been integrated in foam formulations as a means to increase processability and cost efficiency. In recent years, the discovery of INFUSE™ Olefin Block Copolymers (OBC's) has increased the benefits of using ethylene-a-olefin inter-polymers in foam applications. This paper shows that the characteristics that make INFUSE™ OBC's of interest in Crosslinked (XL) foam systems are increased softness, improved shrinkage, and compression set resistance at elevated temperatures. The paper also shows that OBC foams long- term fatigue behavior departs from that of EVA and POE foams with the same cure state. The room temperature data allowed one to draw the following conclusions: (ⅰ) OBC foams showed a more elastic response than EVA and POE as demonstrated by lower final strain and faster recovery after dynamic testing; the elastic response of OBC foams was attributed to its block architecture, and (ⅱ) materials based on short-chain branching (OBC and POE) seemed to recover faster than the foam based on highly branched EVA.
机译:多年来,泡沫塑料行业首选的材料是乙烯-乙酸乙烯酯共聚物(EVA)。该优势基于其柔韧性,粘合性能和发泡窗口。在过去的十年中,乙烯-α-烯烃互聚物(或聚烯烃弹性体(POE))已集成到泡沫配方中,以此来提高可加工性和成本效益。近年来,INFUSE™烯烃嵌段共聚物(OBC's)的发现增加了在泡沫应用中使用乙烯-α-烯烃互聚物的好处。本文表明,使INFUSE™OBC在交联(XL)泡沫系统中倍受关注的特性是增加的柔软度,改善的收缩率和在高温下的抗压缩永久变形性。本文还表明,OBC泡沫的长期疲劳行为不同于具有相同固化状态的EVA和POE泡沫。室温数据可以得出以下结论:(ⅰ)OBC泡沫比EVA和POE表现出更大的弹性响应,这通过较低的最终应变和动态测试后的恢复来证明; OBC泡沫的弹性响应归因于其嵌段结构,基于短链支化(OBC和POE)的(ⅱ)材料似乎比基于高度支化EVA的泡沫恢复得更快。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号