NEW APPROACHES TO THE CL-20/HMX COCRYSTAL A LESS SENSITIVE HIGH POWER EXPLOSIVE

机译：CL-20 / HMX晶体的新方法灵敏的高功率炸药

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Understanding the kinetic and thermodynamic of the formation of the 2:1 cocrystal of CL-20 and HMX is a key factor to optimize crystallization procedures in regard to time and material efficiency as well as crystal purity. Here we describe the temperature and polymorph dependency of the solvent-mediated cocrystallization of HMX and CL-20 in 2-propanol as well as the solubility curves of CL-20 and HMX in acetone/2-propanol mixtures and acetonitrile/2-propanol mixtures at room temperature. The formation time of the cocrystal in unseeded solvent-mediated crystallization shows a strong dependency on the temperature and applied CL-20 polymorph. The received CL-20/HMX cocrystal was found to be less friction sensitive, but more impact sensitive than HMX.

机译：了解CL-20和HMX 2：1共晶形成的动力学和热力学是在时间和材料效率以及晶体纯度方面优化结晶程序的关键因素。在这里，我们描述了溶剂介导的HMX和CL-20在2-丙醇中的共结晶的温度和多晶型依赖性，以及CL-20和HMX在丙酮/ 2-丙醇混合物和乙腈/ 2-丙醇混合物中的溶解度曲线在室温下。在非种子溶剂介导的结晶中，共晶的形成时间显示出对温度和所施加的CL-20多晶型物的强烈依赖性。发现接收到的CL-20 / HMX共晶与HMX相比，对摩擦的敏感性较低，但对冲击的敏感性更高。

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《International annual conference of ICT》|2015年|107.1-107.9|共9页
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Dirk Herrmannsdoerfer; Michael Herrmann; Thomas Heintz;
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1. High power explosive with good sensitivity: A 2:1 cocrystal of CL-20:HMX [J] . Bolton O., Simke L.R., Pagoria P.F., Crystal growth & design . 2012,第9期

机译：高灵敏度的高能炸药：CL-20：HMX的2：1共结晶
2. Transitions from Separately Crystallized CL-20 and HMX to CL-20/HMX Cocrystal Based on Solvent Media [J] . Shanhu Sun, Haobin Zhang, Yu Liu, Crystal growth & design . 2018,第1期

机译：基于溶剂培养基，从单独结晶的CL-20和HMX转变为CL-20 / HMX COCRYSTAL
3. Insights into the roles of two constituents CL-20 and HMX in the CL-20: HMX cocrystal at high pressure: a DFT-D study [J] . Liu Zhichao, Wu Qiong, Zhu Weihua, RSC Advances . 2015,第43期

机译：深入了解CL-20中两种成分CL-20和HMX的作用：高压下的HMX共结晶：DFT-D研究
4. NEW APPROACHES TO THE CL-20/HMX COCRYSTAL A LESS SENSITIVE HIGH POWER EXPLOSIVE [C] . Dirk Herrmannsdoerfer, Michael Herrmann, Thomas Heintz International annual conference of ICT . 2015

机译：CL-20 / HMX COCrystal的新方法是一种敏感的高功率爆炸性
5. Laser ignition of select hexanitrohexaazaisowurtzitane (HNIW or CL-20) cocrystals. [D] . McBain, Andrew W. 2015

机译：激光灼烧选择的六硝基六氮杂异纤锌矿型结构烷烃（HNIW或CL-20）共晶体。
6. Biodegradation of the High Explosive Hexanitrohexaazaiso-wurtzitane (CL-20) [O] . Pelin Karakaya, Christos Christodoulatos, Agamemnon Koutsospyros, 2009

机译：高爆炸性六硝基六氮杂异纤锌矿烷（CL-20）的生物降解
7. Fizičko-hemijske i detonacione karakteristike nitraminskih eksploziva - RDX, HMX i CL-20 / Physico-chemical and detonation properties of nitramine explosives: RDX, HMX and CL-20 [O] . Mirjana Anđelković-Lukić 2002

机译：Fizičko-hemijske i detonacione karakteristike nitraminskih eksploziva - RDX，HmX i CL-20 /硝胺炸药的物理化学和爆炸特性：RDX，HmX和CL-20

NEW APPROACHES TO THE CL-20/HMX COCRYSTAL A LESS SENSITIVE HIGH POWER EXPLOSIVE

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