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Empirical Model for Flammability Limits and Process Safety Evaluation for Ethylene Process under Various Initial Pressures and Temperatures via 20-L-Apparatus

机译:通过20 L设备在各种初始压力和温度下乙烯工艺的易燃性极限和工艺安全性评估的经验模型

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In general, loading concentration of flammable gases between operating process is both imperative for reaction efficiency and necessary for hazard evaluation in the petrochemical industries. In fact, numerous petrochemical manufacturing processes react under high temperature, pressure, fuel, and oxygen concentration scenarios. Conventional steam pyrolysis is the prevailing technique for producing ethylene, and is known to be a non-catalytic, high temperature, as well as low pressure process that thermally cracks the reactant of ethane, propane, or liquid fuels. Therefore, we investigated the flammability limits and explosion pressures of ethane and ethylene under ordinary atmosphere environment, along with upper flammability limits (UFLs) tested within the upper operating limit (UOL) of pure oxygen condition via 20-L-Apparatus. We attempted to establish an empirical model for flammability limits and zone among two initial pressures (1 to 2 atm) and temperatures (approximately 30-200 C) inside the ethylene process for loss prevention concerns. The results showed that an empirical model of UFLs for hydrocarbons as a function of temperature was available; nevertheless, not available for the UOL scenario.
机译:通常,在操作过程之间,可燃气体的负载浓度对于反应效率来说是必不可少的,而且对于石化行业中的危害评估也是必不可少的。实际上,许多石化制造过程会在高温,高压,燃料和氧气浓度较高的情况下发生反应。常规的蒸汽热解是生产乙烯的主要技术,并且已知是非催化的高温以及低压过程,其使乙烷,丙烷或液体燃料的反应物热裂化。因此,我们研究了在普通大气环境下乙烷和乙烯的可燃极限和爆炸压力,以及通过20升装置在纯氧条件下的最高工作极限(UOL)内测试的可燃极限(UFL)。为了防止损失,我们尝试建立乙烯模型内两个初始压力(1-2 atm)和温度(大约30-200 C)之间的可燃性极限和区域的经验模型。结果表明,有一个随温度变化的碳氢化合物超临界流体的经验模型。但是,不适用于UOL场景。

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