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Thermal hazards of benzoyl peroxide and its related process products through theoretical thermodynamics and differential calorimetric technology

机译:通过理论热力学和差示热技术分析过氧化苯甲酰及其相关工艺产品的热危害

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Benzoyl peroxide (BPO) is one of the primary organic peroxides as the initiator, curing agent, or medicine, which plays a crucial role in developing the livelihood industry in the world. However, there are numerous related accidents worldwide, especially fires and explosions related to their unstable properties, the peroxy bond (-O-O-), resulting in economic loss and casualties. BPO can also be identified as a material with autocatalytic reaction characteristics. Therefore, the related processes and their product are the critical points to prevent these kinds of contingencies. The research is based on three types of instruments (non-isothermal, isothermal, and adiabatic calorimetry), including differential scanning calorimetry, thermal activity monitor III, and vent sizing package 2, and theoretical methods to further ensure the thermal hazard level. From the experimental results, the thermal hazard level of BPO added to its related process products from reaction process is much higher than pure BPO.
机译:过氧化苯甲酰(BPO)是作为引发剂,固化剂或药物的主要有机过氧化物之一,在发展世界民生产业中起着至关重要的作用。但是,世界范围内发生了许多相关的事故,特别是与其不稳定特性,过氧键(-O-O-)有关的火灾和爆炸,造成了经济损失和人员伤亡。 BPO也可以被识别为具有自催化反应特性的材料。因此,相关过程及其产品是防止此类意外事件的关键点。该研究基于三种类型的仪器(非等温,等温和绝热量热法),包括差示扫描量热法,热活动监测器III和通风口定型包装2,以及进一步确保热危害水平的理论方法。从实验结果来看,反应过程中添加到其相关过程产品中的BPO的热危害水平远高于纯BPO。

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